{
  "abstract": "To evaluate the electronic and steric properties of carbenes, several techniques have been developed. Herein, we report the use of UV-visible spectroscopy as a stereo-electronic dual probe of carbenes in solution, complementing current methodologies that mostly rely on NMR spectroscopy of rather exotic nuclei and X-ray crystal structures in the solid state. Additionally, we show that carbene–tellurium adducts can act as carbene transfer agents towards other chalcogens and even metals.",
  "abstract_shown": true,
  "affiliations": [
    "UCSD-CNRS Joint Research Laboratory (IRL3555), Department of Chemistry and Biochemistry, University of California San Diego La Jolla CA 92093-0358 USA"
  ],
  "article_type": "research article",
  "arxiv": null,
  "author_total": 6,
  "authors": [
    {
      "affs": [
        0
      ],
      "name": "Wenyi Dong",
      "orcid": "0009-0002-7877-5415"
    },
    {
      "affs": [
        0
      ],
      "name": "Jan Lorkowski",
      "orcid": "0000-0003-3436-1296"
    },
    {
      "affs": [
        0
      ],
      "name": "Mehdi Abdellaoui",
      "orcid": "0000-0002-2719-2095"
    },
    {
      "affs": [
        0
      ],
      "name": "Milan Gembicky",
      "orcid": "0000-0002-3898-1612"
    },
    {
      "affs": [
        0
      ],
      "name": "Mohand Melaimi",
      "orcid": "0000-0003-3553-1381"
    },
    {
      "affs": [
        0
      ],
      "name": "Guy Bertrand",
      "orcid": "0000-0003-2623-2363"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/ekpqqehynbxet.bib",
  "cited_by": 0,
  "doi": "10.1039/d6sc05422f",
  "fulltext_url": "https://pmc.ncbi.nlm.nih.gov/articles/PMC13563393/",
  "id": "ekpqqehynbxet",
  "issns": [
    "2041-6520",
    "2041-6539"
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  "landing_url": "https://hal.science/hal-05834174v1",
  "language": "en",
  "licence": "CC-BY-NC-ND-4.0",
  "licence_label": "CC BY-NC-ND 4.0",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by-nc-nd/4.0/",
  "metadata_licence": null,
  "native_subjects": [
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    [
      "heading",
      "Chemistry"
    ],
    [
      "openalex",
      "3005|Organoselenium and organotellurium chemistry"
    ]
  ],
  "openalex": "W7204460998",
  "pdf_url": "https://hal.science/hal-05834174/document",
  "pmcid": "PMC13563393",
  "pmid": "42729942",
  "published": "2026-08-27",
  "publisher": "The Royal Society of Chemistry",
  "ris": "https://research.draconitic.com/paper/ekpqqehynbxet.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:18:00Z",
      "native_id": "hal-05834174",
      "source": "hal",
      "url": "https://hal.science/hal-05834174v1"
    },
    {
      "first_seen": "2026-10-31T12:23:46Z",
      "native_id": "PMC13563393",
      "source": "pmc",
      "url": "https://doi.org/10.1039/d6sc05422f"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "hal:1.chim.cris",
      "subfield": "inorganic"
    },
    {
      "field": "chemistry",
      "origin": "hal:1.chim.orga",
      "subfield": "organic"
    },
    {
      "field": "chemistry",
      "origin": "hal:1.chim.theo",
      "subfield": "theoretical"
    }
  ],
  "title": "Carbene–tellurium adducts as colorimetric probes for the stereo-electronic profiles of carbenes in solution, and as carbene-transfer agents",
  "title_text": "Carbene–tellurium adducts as colorimetric probes for the stereo-electronic profiles of carbenes in solution, and as carbene-transfer agents",
  "type": "peer-reviewed",
  "updated_at": "2026-11-01T12:20:53Z",
  "url": "https://research.draconitic.com/paper/ekpqqehynbxet",
  "venue": "Chemical Science",
  "versions": []
}