{
  "abstract": "We report an enantioselective approach toward new planar-chiral azaboroles bearing the [2.2]paracyclophane unit and studies of their (chir)optical properties. Fusing the planar-chiral scaffold with a B,N-heterocycle led to the formation of a set of three substances, all of which have interesting chiroptical properties (glum up to 4.7 × 10-3 and BCPL up to 3.1 M-1 cm-1). 1a exhibits superior fluorescence in the solid state unlike the rest of the series.",
  "abstract_shown": true,
  "affiliations": [
    "Department of Organic Chemistry, Faculty of Science, Charles University, Hlavova 8, 128 00Praha 2, Czech Republic.",
    "Department of Inorganic Chemistry, Faculty of Science, Charles University, Hlavova 8, 128 00Praha 2, Czech Republic.",
    "Department of Chemistry, Faculty of Education, J. Selye University, Bratislavská 3322, 945 01Komárno, Slovakia.",
    "Department of Physical and Macromolecular Chemistry, Faculty of Science, Charles University, Hlavova 8, 128 00Prague 2, Czech Republic.",
    "Department of Analytical Chemistry, Faculty of Science, Charles University, Hlavova 8, 128 00Prague 2, Czech Republic.",
    "University of Rennes, CNRS , ISCR-UMR 6226, Rennes35000, France."
  ],
  "article_type": "research article",
  "arxiv": null,
  "author_total": 9,
  "authors": [
    {
      "affs": [
        0
      ],
      "name": "Jakub Koudelka"
    },
    {
      "affs": [
        0
      ],
      "name": "Timothée Cadart",
      "orcid": "0000-0002-7806-5483"
    },
    {
      "affs": [
        1
      ],
      "name": "Ivana Císařová"
    },
    {
      "affs": [
        2
      ],
      "name": "Róbert Gyepes"
    },
    {
      "affs": [
        3
      ],
      "name": "Miroslav Štěpánek"
    },
    {
      "affs": [
        4
      ],
      "name": "Jan Fischer"
    },
    {
      "affs": [
        5
      ],
      "name": "Jhon Sebastian Oviedo Ortiz"
    },
    {
      "affs": [
        5
      ],
      "name": "Jeanne Crassous",
      "orcid": "0000-0002-4037-6067"
    },
    {
      "affs": [
        0
      ],
      "name": "Martin Kotora",
      "orcid": "0000-0003-4491-7091"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/epyhwjacvs0aj.bib",
  "cited_by": 0,
  "doi": "10.1021/acs.orglett.6c03789",
  "fulltext_url": "https://europepmc.org/articles/PMC13682213",
  "id": "epyhwjacvs0aj",
  "issns": [
    "1523-7060",
    "1523-7052"
  ],
  "landing_url": "https://europepmc.org/article/MED/42917698",
  "language": "eng",
  "licence": "CC-BY",
  "licence_label": "CC BY",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "openalex",
      "1605|Synthesis and Properties of Aromatic Compounds"
    ]
  ],
  "openalex": "W7214918905",
  "pdf_url": "https://europepmc.org/articles/PMC13682213?pdf=render",
  "pmcid": "PMC13682213",
  "pmid": "42917698",
  "published": "2026-10-01",
  "publisher": null,
  "ris": "https://research.draconitic.com/paper/epyhwjacvs0aj.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:20:36Z",
      "native_id": "MED:42917698",
      "source": "europepmc",
      "url": "https://europepmc.org/article/MED/42917698"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:1605|Synthesis and Properties of Aromatic Compounds",
      "subfield": "organic"
    }
  ],
  "title": "Design of Small Circularly Polarized Luminescence-Active Planar-Chiral Azaboroles.",
  "title_text": "Design of Small Circularly Polarized Luminescence-Active Planar-Chiral Azaboroles.",
  "type": "peer-reviewed",
  "updated_at": "2026-10-30T12:20:36Z",
  "url": "https://research.draconitic.com/paper/epyhwjacvs0aj",
  "venue": "Organic letters",
  "versions": []
}