{
  "abstract": "The reactivity of triethylaluminum towards salicylaldimine sulfonamides was probed, affording well-defined complexes through consecutive protonolysis of two Al-C bonds by the proligand. These complexes, when combined with an achiral anilinic N-oxide, catalyze the asymmetric addition of trimethylsilylcyanide to a wide range of aldehydes, with good activity and enantioselectivity (up to 91% e.e.). Insertion of the benzaldehyde substrate into the Al-N amido bond was observed, bringing elements for discussion around the nature of the actual active species.",
  "abstract_shown": true,
  "affiliations": [],
  "article_type": null,
  "arxiv": null,
  "author_total": 3,
  "authors": [
    {
      "name": "Jérémy Ternel"
    },
    {
      "name": "Francine Agbossou-Niedercorn"
    },
    {
      "name": "Régis M. Gauvin"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/ev8egft97pxfc.bib",
  "cited_by": 15,
  "doi": "10.1039/c3dt53292e",
  "fulltext_url": null,
  "id": "ev8egft97pxfc",
  "issns": [
    "1477-9226",
    "1477-9234"
  ],
  "landing_url": "https://hal.science/hal-05772956v1",
  "language": "en",
  "licence": "CC-BY-NC-ND-4.0",
  "licence_label": "CC BY-NC-ND 4.0",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by-nc-nd/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "hal",
      "0.chim"
    ],
    [
      "hal",
      "1.chim.cata"
    ],
    [
      "hal",
      "1.chim.coor"
    ],
    [
      "hal",
      "1.chim.orga"
    ],
    [
      "openalex",
      "1605|Asymmetric Synthesis and Catalysis"
    ]
  ],
  "openalex": "W2160113136",
  "pdf_url": "https://hal.science/hal-05772956/document",
  "pmcid": null,
  "pmid": null,
  "published": "2026-10-01",
  "publisher": "Royal Society of Chemistry",
  "ris": "https://research.draconitic.com/paper/ev8egft97pxfc.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:17:45Z",
      "native_id": "hal-05772956",
      "source": "hal",
      "url": "https://hal.science/hal-05772956v1"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "hal:1.chim.cata",
      "subfield": "catalysis"
    },
    {
      "field": "chemistry",
      "origin": "hal:1.chim.coor",
      "subfield": "inorganic"
    },
    {
      "field": "chemistry",
      "origin": "hal:1.chim.orga",
      "subfield": "organic"
    }
  ],
  "title": "Chiral phenoxyimino-amido aluminum complexes for the asymmetric cyanation of aldehydes",
  "title_text": "Chiral phenoxyimino-amido aluminum complexes for the asymmetric cyanation of aldehydes",
  "type": "peer-reviewed",
  "updated_at": "2026-10-30T12:17:45Z",
  "url": "https://research.draconitic.com/paper/ev8egft97pxfc",
  "venue": "Dalton Transactions",
  "versions": []
}