{
  "abstract": "A three-dimensional (3D) supramolecular architecture, {[Zn(dpds)(bdc)]·MeOH·1.5H2O}n (1) (dpds = 1,2-bis(4-pyridyl)disulfide and bdc2– = dianion of 1,4-benzenedicarboxylic acid), assembled by a two-dimensional (2D) layered metal–organic frameworks (MOFs) via interlayer sandwich-type πpyridyl–πbenzene–πpyridyl and πpyridyl–πpyridyl interactions, is examined using scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy to reveal their structures and chemical environments. Compound 1 exhibits a significant water vapor adsorption/desorption isotherm for pretreated 1, which displays a maximum value of 215.5 cm3g–1 at a relative pressure P/P0 = 1.00, corresponding to adsorption of approximately four water molecules per asymmetric unit (ASU). In addition, a series of toxic aromatics, namely, benzene (PhH), toluene (PhCH3), anisole (PhOCH3), and nitrobenzene (PhNO2), can be absorbed by 1 in liquid phases to generate new host–guest compounds, {[Zn(bdc)(dpds)]·0.5Ph·1.5H2O}n (1⊃Ph), {[Zn(bdc)(dpds)]·0.5Ph(CH3)·H2O}n (1⊃PhCH3), {[Zn(bdc)(dpds)]·0.5PhOCH3·1.5H2O}n (1⊃PhOCH3), and {[Zn(bdc)(dpds)]·0.5Ph(NO2)·1.5H2O}n (1⊃PhNO2), which have been indetified by IR, X-ray diffraction method, and TG analysis. Structural characteristics and photoluminescent properties associated with theoretical calculation for 1⊃Ph, 1⊃PhCH3, 1⊃PhOCH3, and 1⊃PhNO2 are studied and discussed.",
  "abstract_shown": true,
  "affiliations": [
    "Soochow University , , ,",
    "National Taiwan University , , ,",
    "National Synchrotron Radiation Research Center , ,"
  ],
  "article_type": "research article",
  "arxiv": null,
  "author_total": 10,
  "authors": [
    {
      "affs": [
        0
      ],
      "name": "Chih-Chieh Wang",
      "orcid": "0000-0001-7286-5597"
    },
    {
      "affs": [
        0
      ],
      "name": "Hsin-Fang Chang"
    },
    {
      "affs": [
        0
      ],
      "name": "Si-Tung Yeh"
    },
    {
      "affs": [
        0
      ],
      "name": "Yu-Chen Chung"
    },
    {
      "affs": [
        0
      ],
      "name": "Shih-I Lu",
      "orcid": "0000-0001-7508-2088"
    },
    {
      "affs": [
        0
      ],
      "name": "Tzu-Hsin Huang"
    },
    {
      "affs": [
        0
      ],
      "name": "Kai-Xin Chen"
    },
    {
      "affs": [
        0
      ],
      "name": "Yi-Ting Hsieh",
      "orcid": "0000-0001-6462-9009"
    },
    {
      "affs": [
        1
      ],
      "name": "Gene-Hsiang Lee"
    },
    {
      "affs": [
        2
      ],
      "name": "Yu-Chun Chuang",
      "orcid": "0000-0002-2879-5381"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/eztwhcgs8vw5r.bib",
  "cited_by": 0,
  "doi": "10.1021/acsomega.6c07748",
  "fulltext_url": "https://pmc.ncbi.nlm.nih.gov/articles/PMC13737972/",
  "id": "eztwhcgs8vw5r",
  "issns": [
    "2470-1343"
  ],
  "landing_url": "https://pubs.acs.org/acsodf/article/doi/10.1021/acsomega.6c07748/5456921/Toxic-Aromatics-Inclusion-and-Water-Vapor",
  "language": "en",
  "licence": "CC-BY-NC-ND-4.0",
  "licence_label": "CC BY-NC-ND 4.0",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by-nc-nd/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "heading",
      "Article"
    ],
    [
      "openalex",
      "1604|Metal-Organic Frameworks: Synthesis and Applications"
    ]
  ],
  "openalex": "W7223317121",
  "pdf_url": "https://pubs.acs.org/doi/pdf/10.1021/acsomega.6c07748",
  "pmcid": "PMC13737972",
  "pmid": "42992075",
  "published": "2026-10-22",
  "publisher": "American Chemical Society (ACS)",
  "ris": "https://research.draconitic.com/paper/eztwhcgs8vw5r.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:18:40Z",
      "native_id": "10.1021/acsomega.6c07748",
      "source": "crossref",
      "url": "https://pubs.acs.org/acsodf/article/doi/10.1021/acsomega.6c07748/5456921/Toxic-Aromatics-Inclusion-and-Water-Vapor"
    },
    {
      "first_seen": "2026-11-09T12:23:03Z",
      "native_id": "PMC13737972",
      "source": "pmc",
      "url": "https://doi.org/10.1021/acsomega.6c07748"
    }
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  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:1604|Metal-Organic Frameworks: Synthesis and Applications",
      "subfield": "inorganic"
    }
  ],
  "title": "Toxic Aromatics Inclusion and Water Vapor Adsorption/Desorption of a 3D Supramolecular Architecture via π–π Assembly of 2D Zn-Based Layered MOFs",
  "title_text": "Toxic Aromatics Inclusion and Water Vapor Adsorption/Desorption of a 3D Supramolecular Architecture via π–π Assembly of 2D Zn-Based Layered MOFs",
  "type": "peer-reviewed",
  "updated_at": "2026-11-09T12:23:03Z",
  "url": "https://research.draconitic.com/paper/eztwhcgs8vw5r",
  "venue": "ACS Omega",
  "versions": []
}