{
  "abstract": "Herein, we report a one-pot, two-step reaction that converts readily available 2-aminobenzimidazoles into scarcely accessible benzo[e][1,2,4]triazines via nitrogen atom insertion. This sequential transformation includes an electrophilic amination step with bench-stable MSH.HOTf, followed by an oxidation with commercial hypervalent iodine reactant. The developed reaction encompasses a wide array of functional handles that could be exploited for post-modification, thus highlighting the synthetic utility of the present work.",
  "abstract_shown": true,
  "affiliations": [],
  "article_type": null,
  "arxiv": null,
  "author_total": 3,
  "authors": [
    {
      "name": "Alexis Leblais"
    },
    {
      "name": "Xavier Moreau"
    },
    {
      "name": "Clément Ghiazza"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/f3qxvb9ymsy1p.bib",
  "cited_by": 0,
  "doi": null,
  "fulltext_url": null,
  "id": "f3qxvb9ymsy1p",
  "issns": [],
  "landing_url": "https://hal.science/hal-05760641v1",
  "language": "en",
  "licence": "CC-BY-NC-ND-4.0",
  "licence_label": "CC BY-NC-ND 4.0",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by-nc-nd/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "hal",
      "0.chim"
    ]
  ],
  "openalex": null,
  "pdf_url": "https://hal.science/hal-05760641/document",
  "pmcid": null,
  "pmid": null,
  "published": "2026-06-30",
  "publisher": null,
  "ris": "https://research.draconitic.com/paper/f3qxvb9ymsy1p.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:17:41Z",
      "native_id": "hal-05760641",
      "source": "hal",
      "url": "https://hal.science/hal-05760641v1"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "hal:0.chim",
      "subfield": "general"
    }
  ],
  "title": "Skeletal editing as synthetic tool to prepare benzo[e][1,2,4]triazines from 2aminobenzimidazoles via nitrogen atom insertion",
  "title_text": "Skeletal editing as synthetic tool to prepare benzo[e][1,2,4]triazines from 2aminobenzimidazoles via nitrogen atom insertion",
  "type": "preprint",
  "updated_at": "2026-10-30T12:17:41Z",
  "url": "https://research.draconitic.com/paper/f3qxvb9ymsy1p",
  "venue": "HAL",
  "versions": []
}