{
  "abstract": "The H2 molecule, a green energy vector, is cleaved without noble metals by an {Fe2S2} complex functionalized via hydroboration of allyldiphenylphosphine. The pair formed by the boron-based Lewis acid and the {FeFe} center functions as a Frustrated Lewis Pair. Computational studies allow the proposed mechanism of intramolecular cooperative H2 splitting to be rationalized.",
  "abstract_shown": true,
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  "article_type": null,
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  "author_total": 7,
  "authors": [
    {
      "name": "Victor Monnot"
    },
    {
      "name": "Jean-Baptiste Breton"
    },
    {
      "name": "Federica Arrigoni"
    },
    {
      "name": "Kevin Maineri"
    },
    {
      "name": "Giuseppe Zampella"
    },
    {
      "name": "Philippe Schollhammer"
    },
    {
      "name": "Lucile Chatelain"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/fdjyx20jafn7d.bib",
  "cited_by": 0,
  "doi": "10.1039/d6cc05801a",
  "fulltext_url": null,
  "id": "fdjyx20jafn7d",
  "issns": [
    "1359-7345",
    "1364-548X"
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  "landing_url": "https://hal.science/hal-05795020v1",
  "language": "en",
  "licence": "CC-BY-NC-4.0",
  "licence_label": "CC BY-NC 4.0",
  "licence_source": "article",
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  "native_subjects": [
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      "openalex",
      "2105|Metalloenzymes and iron-sulfur proteins"
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  "openalex": "W7220422820",
  "pdf_url": "https://hal.science/hal-05795020/document",
  "pmcid": null,
  "pmid": null,
  "published": "2026-10-05",
  "publisher": "Royal Society of Chemistry",
  "ris": "https://research.draconitic.com/paper/fdjyx20jafn7d.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:17:54Z",
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  "subjects": [
    {
      "field": "chemistry",
      "origin": "journal-openalex:1605|Supramolecular Chemistry and Complexes",
      "subfield": "organic"
    }
  ],
  "title": "H2 Activation by a Borane-Modified [FeFe]-Hydrogenase Model forming an Intramolecular Frustrated Lewis Pair",
  "title_text": "H2 Activation by a Borane-Modified [FeFe]-Hydrogenase Model forming an Intramolecular Frustrated Lewis Pair",
  "type": "peer-reviewed",
  "updated_at": "2026-10-30T12:17:54Z",
  "url": "https://research.draconitic.com/paper/fdjyx20jafn7d",
  "venue": "Chemical Communications",
  "versions": []
}