{
  "abstract": "In situ growth of Mn₂O₃ on the surface of the iron mesh was performed hydrothermally to prepare novel catalysts with enhanced toluene oxidation performance. The effect of exposed crystal planes of catalysts, regulated by manganese concentration, on the catalytic performance of toluene oxidation was systematically studied using various characterization techniques, including XRD, SEM, TEM, Raman, H₂-TPR, and XPS. The 1.2MnO x /IM catalyst exhibited superior toluene oxidation performance, attributed to Mn₂O₃ (111)- facet-induced synergistic effects between its super-low-temperature oxidation capability and abundant oxygen vacancies. DFT calculations indicated that the catalyst with an exposed Mn₂O₃ (111) crystal plane has stronger toluene/O₂ adsorption and weaker CO₂ adsorption, demonstrating its excellent catalytic activity and stability. The work opens an exploration of the role of the crystal plane in monolithic catalysts and provides a theoretical basis for monolithic catalysts for VOC oxidation.",
  "abstract_shown": true,
  "affiliations": [
    "State Key Laboratory of Separation Membranes and Membrane Processes, Tianjin Key Laboratory of Green Chemical Technology and Process Engineering, School of Material Science and Engineering, Tiangong University Tianjin 300387 China liudan@tiangong.edu.cn guijianzhou@tiangong.edu.cn.",
    "Ningxia Coal Industry Co. Ltd, CHN ENERGY Yinchuan 750011 P. R. China.",
    "Shandong Haihua Co., Ltd Weifang Shandong 262737 China.",
    "School of Chemical Engineering and Technology, Tiangong University Tianjin 300387 China."
  ],
  "article_type": "research article",
  "arxiv": null,
  "author_total": 6,
  "authors": [
    {
      "affs": [
        0,
        1
      ],
      "name": "Kewang Huang"
    },
    {
      "affs": [
        2
      ],
      "name": "Jianshen Wang",
      "orcid": "0009-0003-1438-9272"
    },
    {
      "affs": [
        0
      ],
      "name": "Gangguo Zhao",
      "orcid": "0009-0008-9948-1567"
    },
    {
      "affs": [
        1
      ],
      "name": "Xiaojing Gui"
    },
    {
      "affs": [
        0
      ],
      "name": "Dan Liu",
      "orcid": "0000-0002-0945-1663"
    },
    {
      "affs": [
        0,
        3
      ],
      "name": "Jianzhou Gui",
      "orcid": "0000-0002-8406-9886"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/fp1kv1rfya46d.bib",
  "cited_by": 0,
  "doi": "10.1039/d6ra07826e",
  "fulltext_url": "https://www.ncbi.nlm.nih.gov/pmc/articles/PMC13726628/?tool=EBI",
  "id": "fp1kv1rfya46d",
  "issns": [
    "2046-2069"
  ],
  "landing_url": "https://europepmc.org/article/PMC/PMC13726628",
  "language": "eng",
  "licence": "CC-BY",
  "licence_label": "CC BY",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "heading",
      "Chemistry"
    ],
    [
      "openalex",
      "2505|Catalytic Processes in Materials Science"
    ]
  ],
  "openalex": "W7225088545",
  "pdf_url": "https://www.ncbi.nlm.nih.gov/pmc/articles/PMC13726628/pdf/?tool=EBI",
  "pmcid": "PMC13726628",
  "pmid": "42974499",
  "published": "2026-11-02",
  "publisher": "Royal Society of Chemistry",
  "ris": "https://research.draconitic.com/paper/fp1kv1rfya46d.ris",
  "sources": [
    {
      "first_seen": "2026-11-03T15:20:51Z",
      "native_id": "PMC:PMC13726628",
      "source": "europepmc",
      "url": "https://europepmc.org/article/PMC/PMC13726628"
    },
    {
      "first_seen": "2026-11-04T15:20:47Z",
      "native_id": "MED:42974499",
      "source": "europepmc",
      "url": "https://europepmc.org/article/MED/42974499"
    },
    {
      "first_seen": "2026-11-05T12:22:55Z",
      "native_id": "PMC13726628",
      "source": "pmc",
      "url": "https://doi.org/10.1039/d6ra07826e"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:2505|Catalytic Processes in Materials Science",
      "subfield": "materials-polymers"
    }
  ],
  "title": "Insights into the effect of exposed Mn2O3 crystal planes on toluene oxidation over MnOx/IM monolithic catalysts",
  "title_text": "Insights into the effect of exposed Mn2O3 crystal planes on toluene oxidation over MnOx/IM monolithic catalysts",
  "type": "peer-reviewed",
  "updated_at": "2026-11-05T12:22:55Z",
  "url": "https://research.draconitic.com/paper/fp1kv1rfya46d",
  "venue": "RSC advances",
  "versions": []
}