{
  "abstract": "A persistent C-phosphonio boratavinyl anion 1 has been successfully synthesized. This boron-containing vinyl-lithium 1, featuring a vinyl carbon with a negative charge (-1.59), considerably higher than that of carbon analogue 7 (-0.76), exhibits strongly nucleophilic and basic properties, as demonstrated by the results of rapid reactions with H 2 (10 bar, 15 min or 1 bar, 2 h at RT) and C 6 F 6 (1 equiv., 15 min at -80 • C). The reactions of boratavinyl anion 1 with electrophiles offer a convenient route for the introduction of a borata-alkene-based bulky and σ,π-double-donating substituent, enabling to efficiently stabilize reactive intermediates such as halogenogermylenes. Furthermore, the reaction with CO 2 takes place at the borata-alkene moiety, rather than at the P-ylide function, resulting in the double insertion of CO 2 into the B─C bond to afford a unique cyclic P-ylide 13.",
  "abstract_shown": true,
  "affiliations": [],
  "article_type": null,
  "arxiv": null,
  "author_total": 8,
  "authors": [
    {
      "name": "Huihui Xu"
    },
    {
      "name": "Aurora Rodríguez‐álvarez"
    },
    {
      "name": "Md Jabed Hossain"
    },
    {
      "name": "Antoine Baceiredo"
    },
    {
      "name": "Eddy Maerten"
    },
    {
      "name": "Nathalie Saffon‐merceron"
    },
    {
      "name": "Vicenç Branchadell"
    },
    {
      "name": "Tsuyoshi Kato"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/ftk7ckd06hv4f.bib",
  "cited_by": 0,
  "doi": "10.1002/anie.2724882",
  "fulltext_url": null,
  "id": "ftk7ckd06hv4f",
  "issns": [
    "1433-7851",
    "1521-3773"
  ],
  "landing_url": "https://hal.science/hal-05768598v1",
  "language": "en",
  "licence": "CC-BY-NC-ND-4.0",
  "licence_label": "CC BY-NC-ND 4.0",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by-nc-nd/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "hal",
      "0.chim"
    ],
    [
      "openalex",
      "1604|Synthesis and characterization of novel inorganic/organometallic compounds"
    ]
  ],
  "openalex": "W7171536931",
  "pdf_url": "https://hal.science/hal-05768598/document",
  "pmcid": null,
  "pmid": null,
  "published": "2026-07-28",
  "publisher": "Wiley-VCH Verlag",
  "ris": "https://research.draconitic.com/paper/ftk7ckd06hv4f.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:17:42Z",
      "native_id": "hal-05768598",
      "source": "hal",
      "url": "https://hal.science/hal-05768598v1"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:1604|Synthesis and characterization of novel inorganic/organometallic compounds",
      "subfield": "inorganic"
    }
  ],
  "title": "Isolable C‐Phosphonio‐Boratavinyl Anion",
  "title_text": "Isolable C‐Phosphonio‐Boratavinyl Anion",
  "type": "peer-reviewed",
  "updated_at": "2026-10-30T12:17:42Z",
  "url": "https://research.draconitic.com/paper/ftk7ckd06hv4f",
  "venue": "Angewandte Chemie International Edition",
  "versions": []
}