{
  "abstract": "Metal-ion-assisted Schiff-base condensation enabled the isolation of the complex [Dy(LN6prop)(CH3COO)2](BPh4) (1), which undergoes a ligand exchange reaction with triphenylsilanolate to yield [Dy(LN6prop)(CH3COO)(OSiPh3)](BPh4)·0.5CH2Cl2 (2·0.5CH2Cl2). The crystal structure of 2·0.5CH2Cl2 reveals that the Dy3+ ion is coordinated in an N6O3 environment, adopting a distorted capped square antiprism geometry. 2·0.5CH2Cl2 is a single ion magnet, exhibiting magnetic relaxation in the 2-22 K range with an energy barrier of 465 K, consistent with ab initio calculations and luminescent measurements. 2·0.5CH2Cl2 also functions as a luminescent thermometer with maximum sensitivity SrΔ of 1% K-1 at 12 K. In addition, 2·0.5CH2Cl2 also shows magneto-thermometry, based on magnetic relaxation time (τ) and inverse magnetic susceptibility (1/χ). This magneto-thermometer achieves relatively high magneto-thermal sensitivities (Smax) of 9.3 % K-1 (Sr1/χ) at 10 K and 20 % K-1 (Srτ) at 9 K, while both Sr parameters remain well above 1% K-1 across the entire single-molecule magnet (SMM) operating range. Overall, 2·0.5CH2Cl2 constitutes a bifunctional molecular material, integrating SMM behavior with efficient dual-mode luminescent and magnetic thermometry.",
  "abstract_shown": true,
  "affiliations": [
    "Departamento de Química Inorgánica, Facultade de Química, Universidade de Santiago de Compostela, 15782Santiago de Compostela, Spain.",
    "Institute of Materials (iMATUS), Universidade de Santiago de Compostela, 15782Santiago de Compostela, Spain.",
    "Phantom-g, CICECO-Aveiro Institute of Materials, Physics Department, University of Aveiro, 3810-193, Aveiro, Portugal.",
    "Departamento de Química de los Materiales, Facultad de Química y Biología, Universidad de Santiago de Chile, Casilla 40, Correo33, Santiago, Chile."
  ],
  "article_type": "research article",
  "arxiv": null,
  "author_total": 9,
  "authors": [
    {
      "affs": [
        0,
        1
      ],
      "name": "Paula Oreiro-Martínez",
      "orcid": "0000-0003-1199-5472"
    },
    {
      "affs": [
        0
      ],
      "name": "Cristina González-Barreira",
      "orcid": "0000-0001-9975-597X"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Julio Corredoira-Vázquez",
      "orcid": "0000-0002-7806-179X"
    },
    {
      "affs": [
        0
      ],
      "name": "Ana M García-Deibe",
      "orcid": "0000-0001-9127-0740"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Jesús Sanmartín-Matalobos",
      "orcid": "0000-0002-9971-4657"
    },
    {
      "affs": [
        2
      ],
      "name": "Carlos D S Brites",
      "orcid": "0000-0001-9636-2628"
    },
    {
      "affs": [
        2
      ],
      "name": "Luis D Carlos",
      "orcid": "0000-0003-4747-6535"
    },
    {
      "affs": [
        3
      ],
      "name": "Daniel Aravena",
      "orcid": "0000-0003-3140-4852"
    },
    {
      "affs": [
        0,
        1
      ],
      "name": "Matilde Fondo",
      "orcid": "0000-0002-7535-946X"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/fw5824ey7f8re.bib",
  "cited_by": 0,
  "doi": "10.1021/acs.inorgchem.6c02533",
  "fulltext_url": "https://europepmc.org/articles/PMC13599389",
  "id": "fw5824ey7f8re",
  "issns": [
    "0020-1669",
    "1520-510X"
  ],
  "landing_url": "https://europepmc.org/article/MED/42916210",
  "language": "eng",
  "licence": "CC-BY",
  "licence_label": "CC BY",
  "licence_source": "article",
  "licence_url": "https://creativecommons.org/licenses/by/4.0/",
  "metadata_licence": null,
  "native_subjects": [
    [
      "openalex",
      "2504|Magnetism in coordination complexes"
    ]
  ],
  "openalex": "W7212243161",
  "pdf_url": "https://europepmc.org/articles/PMC13599389?pdf=render",
  "pmcid": "PMC13599389",
  "pmid": "42916210",
  "published": "2026-09-01",
  "publisher": null,
  "ris": "https://research.draconitic.com/paper/fw5824ey7f8re.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:21:02Z",
      "native_id": "MED:42916210",
      "source": "europepmc",
      "url": "https://europepmc.org/article/MED/42916210"
    }
  ],
  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:2504|Magnetism in coordination complexes",
      "subfield": "materials-polymers"
    }
  ],
  "title": "A Dy3+ Single-Molecule Magnet as a Dual-Mode Luminescent and Magnetic Thermometer.",
  "title_text": "A Dy3+ Single-Molecule Magnet as a Dual-Mode Luminescent and Magnetic Thermometer.",
  "type": "peer-reviewed",
  "updated_at": "2026-10-30T12:21:02Z",
  "url": "https://research.draconitic.com/paper/fw5824ey7f8re",
  "venue": "Inorganic chemistry",
  "versions": []
}