{
  "abstract": "nachtsheim@uni-bremen.de Abstract O-Phosphorylation of a thyroxine derivative redirects mCPBA oxidation from the internal iodine to a terminal one. A two-step oxidation-hydrolysis sequence delivers the phosphate-stabilised aryl(hydroxy)iodonium salt, whose regiochemistry is established by 3 J-CP-coupling.",
  "abstract_shown": true,
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  "article_type": null,
  "arxiv": null,
  "author_total": 3,
  "authors": [
    {
      "name": "Marcel Sancken"
    },
    {
      "name": "Felix Schindler"
    },
    {
      "name": "Boris J. Nachtsheim",
      "orcid": "0000-0002-3759-2770"
    }
  ],
  "bibtex": "https://research.draconitic.com/paper/fzm5hpb72yg0y.bib",
  "cited_by": 0,
  "doi": "10.26434/chemrxiv.15009163/v1",
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  "id": "fzm5hpb72yg0y",
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  "language": null,
  "licence": "CC-BY-NC",
  "licence_label": "CC BY-NC",
  "licence_source": "journal",
  "licence_url": "https://creativecommons.org/licenses/by-nc/4.0/",
  "metadata_licence": null,
  "native_subjects": [
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      "openalex",
      "1605|Oxidative Organic Chemistry Reactions"
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  "pdf_url": "https://chemrxiv.org/doi/pdf/10.26434/chemrxiv.15009163/v1",
  "pmcid": null,
  "pmid": null,
  "published": "2026-09-21",
  "publisher": "American Chemical Society (ACS)",
  "ris": "https://research.draconitic.com/paper/fzm5hpb72yg0y.ris",
  "sources": [
    {
      "first_seen": "2026-10-30T12:17:19Z",
      "native_id": "10.26434/chemrxiv.15009163",
      "source": "chemrxiv",
      "url": "https://chemrxiv.org/doi/full/10.26434/chemrxiv.15009163/v1"
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  "subjects": [
    {
      "field": "chemistry",
      "origin": "openalex:1605|Oxidative Organic Chemistry Reactions",
      "subfield": "organic"
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  ],
  "title": "Redirecting Iodine Oxidation in Thyroxine by O-Phosphorylation",
  "title_text": "Redirecting Iodine Oxidation in Thyroxine by O-Phosphorylation",
  "type": "preprint",
  "updated_at": "2026-10-30T12:17:19Z",
  "url": "https://research.draconitic.com/paper/fzm5hpb72yg0y",
  "venue": "ChemRxiv",
  "versions": []
}