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Peer-reviewedCC BYScientific Reports

Multi-cell quasi-solid-state photo-supercapacitor integrating ZnO, ZnO/g-C₃N₄, and MnO₂ for simultaneous light harvesting and energy storage

  1. 1Micro and Nanotechnology Graduate Program, TOBB University of Economics and Technology
  2. 2Fotontek Optical Communication Ltd. Sti

Abstract

Solar energy intermittency requires compact devices for simultaneous photon-to-charge conversion and storage. Conventional photo-supercapacitors (PSCs) are limited by poor UV response in MnO₂-based systems, restricted visible-light absorption of wide-bandgap oxides, and charge recombination in tandem electrodes. This study addresses these challenges through a multi-cell quasi-solid-state PSC that integrates separate ZnO, ZnO/g-C₃N₄, and MnO₂ cells, enabling efficient UV and sunlight harvesting while avoiding recombination losses. The optimized device delivered a specific capacitance of 32.56 F g-1, Coulombic efficiency of 81.86%, power density of 9375 W kg-1, and energy density of 18.09 Wh kg-1 under illumination. It powered a red LED for 75 s after bias charging and operated a digital clock for 30 min when charged under direct sunlight, demonstrating strong potential for autonomous solar energy systems.

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BibTeX
@article{colak2026multicell,
  title = {{Multi-cell quasi-solid-state photo-supercapacitor integrating ZnO, ZnO/g-C₃N₄, and MnO₂ for simultaneous light harvesting and energy storage}},
  author = {Tuluhan Olcayto Colak and Ecenaz Yaman and Cigdem Tuc Altaf and Mehmet Sankir and Nurdan Demirci Sankir},
  journal = {Scientific Reports},
  year = {2026},
  month = jul,
  doi = {10.1038/s41598-026-61716-y},
  url = {https://doi.org/10.1038/s41598-026-61716-y},
  note = {CC BY},
}
RIS
TY  - JOUR
TI  - Multi-cell quasi-solid-state photo-supercapacitor integrating ZnO, ZnO/g-C₃N₄, and MnO₂ for simultaneous light harvesting and energy storage
AU  - Tuluhan Olcayto Colak
AU  - Ecenaz Yaman
AU  - Cigdem Tuc Altaf
AU  - Mehmet Sankir
AU  - Nurdan Demirci Sankir
PY  - 2026
DA  - 2026/07/01
JO  - Scientific Reports
DO  - 10.1038/s41598-026-61716-y
UR  - https://doi.org/10.1038/s41598-026-61716-y
AB  - Solar energy intermittency requires compact devices for simultaneous photon-to-charge conversion and storage. Conventional photo-supercapacitors (PSCs) are limited by poor UV response in MnO₂-based systems, restricted visible-light absorption of wide-bandgap oxides, and charge recombination in tandem electrodes. This study addresses these challenges through a multi-cell quasi-solid-state PSC that integrates separate ZnO, ZnO/g-C₃N₄, and MnO₂ cells, enabling efficient UV and sunlight harvesting while avoiding recombination losses. The optimized device delivered a specific capacitance of 32.56 F g-1, Coulombic efficiency of 81.86%, power density of 9375 W kg-1, and energy density of 18.09 Wh kg-1 under illumination. It powered a red LED for 75 s after bias charging and operated a digital clock for 30 min when charged under direct sunlight, demonstrating strong potential for autonomous solar energy systems.
SN  - 2045-2322
ER  -