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Peer-reviewedCC BY 4.0Molecules

Non-Targeted Electronic-Nose Fingerprinting and Microscopic Imaging for Leather Classification via Transformer-Based Multimodal Fusion

  1. 1College of Information Science and Technology, Beijing University of Chemical Technology, Beijing 100029, China
  2. 2School of Biomedical Engineering, Capital Medical University, Beijing 100069, China

Abstract

The rapid, non-destructive screening of leather authenticity requires analytical measurements that capture complementary volatile-response and microstructural information. This study developed RLFormer, a multimodal workflow combining cross-responsive metal-oxide-semiconductor electronic-nose (E-nose) fingerprints with microscopic surface images. Four classes—synthetic, pig, sheep, and cattle leather—were represented by 100 specimens each and measured during a standardized 10-day campaign. The relative standard deviations of the category-level daily mean E-nose responses ranged from 1.4 to 13.3% (global mean, 6.18%), and a variance-component analysis revealed a progressive between-day response attenuation common to all categories. A ResNet50 visual encoder and a two-layer long short-term memory (LSTM) encoder generated modality-specific representations that were integrated by a transformer encoder. With days 1–7 used for training and days 8–10 for testing, RLFormer achieved an accuracy of 97.67±2.16% and a Cohen’s kappa of 0.9689±0.0288 over five random seeds, compared with an 87.50±2.50% accuracy for direct ResNet50–LSTM fusion. The results demonstrate the value of combining non-targeted volatile-response patterns with microscopic texture for rapid leather classification. The workflow is intended for screening rather than compound-specific identification and requires independent validation before deployment.

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BibTeX
@article{wang2026nontargeted,
  title = {{Non-Targeted Electronic-Nose Fingerprinting and Microscopic Imaging for Leather Classification via Transformer-Based Multimodal Fusion}},
  author = {Xiaoran Wang and Juan Chen and Yu Gu},
  journal = {Molecules},
  year = {2026},
  month = oct,
  doi = {10.3390/molecules31213879},
  url = {https://www.mdpi.com/1420-3049/31/21/3879},
  note = {CC BY 4.0},
}
RIS
TY  - JOUR
TI  - Non-Targeted Electronic-Nose Fingerprinting and Microscopic Imaging for Leather Classification via Transformer-Based Multimodal Fusion
AU  - Xiaoran Wang
AU  - Juan Chen
AU  - Yu Gu
PY  - 2026
DA  - 2026/10/27
JO  - Molecules
DO  - 10.3390/molecules31213879
UR  - https://www.mdpi.com/1420-3049/31/21/3879
AB  - The rapid, non-destructive screening of leather authenticity requires analytical measurements that capture complementary volatile-response and microstructural information. This study developed RLFormer, a multimodal workflow combining cross-responsive metal-oxide-semiconductor electronic-nose (E-nose) fingerprints with microscopic surface images. Four classes—synthetic, pig, sheep, and cattle leather—were represented by 100 specimens each and measured during a standardized 10-day campaign. The relative standard deviations of the category-level daily mean E-nose responses ranged from 1.4 to 13.3% (global mean, 6.18%), and a variance-component analysis revealed a progressive between-day response attenuation common to all categories. A ResNet50 visual encoder and a two-layer long short-term memory (LSTM) encoder generated modality-specific representations that were integrated by a transformer encoder. With days 1–7 used for training and days 8–10 for testing, RLFormer achieved an accuracy of 97.67±2.16% and a Cohen’s kappa of 0.9689±0.0288 over five random seeds, compared with an 87.50±2.50% accuracy for direct ResNet50–LSTM fusion. The results demonstrate the value of combining non-targeted volatile-response patterns with microscopic texture for rapid leather classification. The workflow is intended for screening rather than compound-specific identification and requires independent validation before deployment.
SN  - 1420-3049
ER  -