Functionalization‐Mediated Synthesis of Bridge‐Coordinated Fe Atoms on MoS ₂ Nanosheets for PEM Water Electrolyzers
Abstract
Transition metal chalcogenides are among the most promising platinum group metal-free (PGM-free) catalysts for hydrogen production in a proton exchange membrane water electrolyzer (PEMWE). However, achieving both high activity and long-term stability remains a critical challenge for their practical deployment. Here, we report a functionalization-mediated synthesis of molybdenum sulfide, containing bridge-coordinated Fe atoms (b-Fe-MoS 2 ), achieving enhanced catalytic performance for the hydrogen evolution reaction (HER). Combined detailed spectroscopic and electrochemical characterizations revealed that cysteine functionalization promotes the anchoring of Fe atoms in a bridge-like coordination environment on the MoS 2 nanosheets, resulting in tunable electron density near the Fe sites and improved robustness of the atomic sites, as supported by our operando and postmortem investigations. The experimental results are complemented with density functional theory (DFT) calculations revealing that the unique coordination environment of Fe atoms modulates the hydrogen adsorption free energy. When integrated in a 25 cm 2 catalyst-coated membrane PEM water electrolyzer, b-Fe-MoS 2 achieved remarkable performance, delivering 1.55 A cm -2 at 2 V and showed stable operation over 360 h following initial activation. These results demonstrate the effectiveness of the functionalization-mediated approach for preparing robust HER catalysts and highlight the potential of bridge-coordinated Fe-MoS 2 cathodes for PGM-free PEM water electrolyzers.
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BibTeX
@article{anfar2026functionalizationmediated,
title = {{Functionalization‐Mediated Synthesis of Bridge‐Coordinated Fe Atoms on MoS ₂ Nanosheets for PEM Water Electrolyzers}},
author = {Zakaria Anfar and Haitham Maslouh and Yuwei Yang and Mathilde Moderne and Jiefeng Liu and Loïc Assaud and Mikhael Bechelany and Chrystelle Salameh and Kun Qi and Yuying Meng and Huali Wu and Ji Li and Nicholas M Bedford and Damien Voiry},
journal = {Angewandte Chemie International Edition},
year = {2026},
month = jul,
doi = {10.1002/anie.6960943},
url = {https://hal.umontpellier.fr/hal-05757326v1},
note = {CC BY 4.0},
}
RIS
TY - JOUR
TI - Functionalization‐Mediated Synthesis of Bridge‐Coordinated Fe Atoms on MoS ₂ Nanosheets for PEM Water Electrolyzers
AU - Zakaria Anfar
AU - Haitham Maslouh
AU - Yuwei Yang
AU - Mathilde Moderne
AU - Jiefeng Liu
AU - Loïc Assaud
AU - Mikhael Bechelany
AU - Chrystelle Salameh
AU - Kun Qi
AU - Yuying Meng
AU - Huali Wu
AU - Ji Li
AU - Nicholas M Bedford
AU - Damien Voiry
PY - 2026
DA - 2026/07/27
JO - Angewandte Chemie International Edition
DO - 10.1002/anie.6960943
UR - https://hal.umontpellier.fr/hal-05757326v1
AB - Transition metal chalcogenides are among the most promising platinum group metal-free (PGM-free) catalysts for hydrogen production in a proton exchange membrane water electrolyzer (PEMWE). However, achieving both high activity and long-term stability remains a critical challenge for their practical deployment. Here, we report a functionalization-mediated synthesis of molybdenum sulfide, containing bridge-coordinated Fe atoms (b-Fe-MoS 2 ), achieving enhanced catalytic performance for the hydrogen evolution reaction (HER). Combined detailed spectroscopic and electrochemical characterizations revealed that cysteine functionalization promotes the anchoring of Fe atoms in a bridge-like coordination environment on the MoS 2 nanosheets, resulting in tunable electron density near the Fe sites and improved robustness of the atomic sites, as supported by our operando and postmortem investigations. The experimental results are complemented with density functional theory (DFT) calculations revealing that the unique coordination environment of Fe atoms modulates the hydrogen adsorption free energy. When integrated in a 25 cm 2 catalyst-coated membrane PEM water electrolyzer, b-Fe-MoS 2 achieved remarkable performance, delivering 1.55 A cm -2 at 2 V and showed stable operation over 360 h following initial activation. These results demonstrate the effectiveness of the functionalization-mediated approach for preparing robust HER catalysts and highlight the potential of bridge-coordinated Fe-MoS 2 cathodes for PGM-free PEM water electrolyzers.
SN - 1433-7851
SN - 1521-3773
ER -