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Peer-reviewedCC BYRSC advances

Well-defined alkali metal catalysts for selective reduction of functionalized esters and carbonyl compounds via hydrosilylation.

  • Guoqi Zhang1
  • Paulina Hiyaev1
  • Haiyu Mei1
  • Marilyn Chocho1
  1. 1Department of Sciences, John Jay College and PhD Program in Chemistry, The Graduate Center, The City University of New York New York NY 10019 USA [email protected].
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Abstract

Well-defined 2,2':6',2″-terpyridine-ligated alkali metal complexes catalysed the chemo- and regioselective reduction of esters and carbonyl compounds through hydrosilylation under mild conditions. Unusual regioselectivity on the alkene group was observed for the reduction of α,β-unsaturated esters.

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Cite

BibTeXRIS
BibTeX
@article{zhang2026welldefined,
  title = {{Well-defined alkali metal catalysts for selective reduction of functionalized esters and carbonyl compounds via hydrosilylation.}},
  author = {Guoqi Zhang and Paulina Hiyaev and Haiyu Mei and Marilyn Chocho},
  journal = {RSC advances},
  year = {2026},
  month = oct,
  doi = {10.1039/d6ra06630e},
  url = {https://europepmc.org/article/MED/42857540},
  note = {CC BY},
}
RIS
TY  - JOUR
TI  - Well-defined alkali metal catalysts for selective reduction of functionalized esters and carbonyl compounds via hydrosilylation.
AU  - Guoqi Zhang
AU  - Paulina Hiyaev
AU  - Haiyu Mei
AU  - Marilyn Chocho
PY  - 2026
DA  - 2026/10/05
JO  - RSC advances
DO  - 10.1039/d6ra06630e
UR  - https://europepmc.org/article/MED/42857540
AB  - Well-defined 2,2':6',2″-terpyridine-ligated alkali metal complexes catalysed the chemo- and regioselective reduction of esters and carbonyl compounds through hydrosilylation under mild conditions. Unusual regioselectivity on the alkene group was observed for the reduction of α,β-unsaturated esters.
SN  - 2046-2069
ER  -