Liquid-liquid phase transitions in dipolar liquids. Insights into Supercooled Water
Abstract
Dipolar liquids combine two coupled degrees of freedom, translational and dipolar. Intriguingly, these two sectors can reside in distinct thermodynamic states, with the state of one sector possibly favoring a specific state of the other. The onset of ferroelectric order in dipolar liquids is an example of this mutual stabilization. Since this coupling is often encoded in interaction potentials, projecting out one sector to derive an effective interaction for the other can uncover the microscopic mechanism underlying this phenomenon. A coarse-grained theory in which the distance between nearest-neighbor particles depends on their dipolar interaction through a density-dependent mechanical compliance shows that a ferroelectric transition can trigger a liquid-liquid transition. It also predicts a first-order liquid-liquid transition in the paraelectric phase that can in turn induce ferroelectric ordering. The anisotropic dipolar-dependent soft-core interaction is shown to lead to an effective Jagla-like isotropic two-length-scale interaction, known to support liquid-liquid phase transitions. Here, however, the two-length-scale pattern depends on density and dipolar configuration, becoming sensitive to dipolar order. Analysis of supercooled TIP4P/Ice water numerical simulations shows that first-coordination-shell features of pair correlation functions are sensitive to dipolar interaction, supporting the coarse-grained theory foundations. Comparison of low- and high-density liquid water reveals enhanced spatial anisotropy of the first coordination shell in the low-density liquid, with increased effective excluded volume, showing that the liquid-liquid transition involves structural changes within the first shell, beyond reorganization of the interstitial region and tetrahedral order. These findings point to a role for dipolar interactions in supercooled water liquid-liquid phase transition.
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BibTeX
@misc{izzo2026liquidliquid,
title = {{Liquid-liquid phase transitions in dipolar liquids. Insights into Supercooled Water}},
author = {Maria Grazia Izzo},
howpublished = {arXiv},
year = {2026},
month = sep,
doi = {10.48550/arxiv.2609.02666},
eprint = {2609.02666},
archivePrefix = {arXiv},
url = {https://arxiv.org/abs/2609.02666},
note = {CC BY-NC-ND 4.0},
}
RIS
TY - UNPB
TI - Liquid-liquid phase transitions in dipolar liquids. Insights into Supercooled Water
AU - Maria Grazia Izzo
PY - 2026
DA - 2026/09/02
PB - arXiv
DO - 10.48550/arxiv.2609.02666
UR - https://arxiv.org/abs/2609.02666
AB - Dipolar liquids combine two coupled degrees of freedom, translational and dipolar. Intriguingly, these two sectors can reside in distinct thermodynamic states, with the state of one sector possibly favoring a specific state of the other. The onset of ferroelectric order in dipolar liquids is an example of this mutual stabilization. Since this coupling is often encoded in interaction potentials, projecting out one sector to derive an effective interaction for the other can uncover the microscopic mechanism underlying this phenomenon. A coarse-grained theory in which the distance between nearest-neighbor particles depends on their dipolar interaction through a density-dependent mechanical compliance shows that a ferroelectric transition can trigger a liquid-liquid transition. It also predicts a first-order liquid-liquid transition in the paraelectric phase that can in turn induce ferroelectric ordering. The anisotropic dipolar-dependent soft-core interaction is shown to lead to an effective Jagla-like isotropic two-length-scale interaction, known to support liquid-liquid phase transitions. Here, however, the two-length-scale pattern depends on density and dipolar configuration, becoming sensitive to dipolar order. Analysis of supercooled TIP4P/Ice water numerical simulations shows that first-coordination-shell features of pair correlation functions are sensitive to dipolar interaction, supporting the coarse-grained theory foundations. Comparison of low- and high-density liquid water reveals enhanced spatial anisotropy of the first coordination shell in the low-density liquid, with increased effective excluded volume, showing that the liquid-liquid transition involves structural changes within the first shell, beyond reorganization of the interstitial region and tetrahedral order. These findings point to a role for dipolar interactions in supercooled water liquid-liquid phase transition.
ER -