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Peer-reviewedCC BY 4.0Catalysts

One-Step Molten Salt Assistant Synthesis of Ni Nanoparticles Incorporated on Carbon Materials as Hydrogen Evolution Electrocatalyst

  1. 1Hubei Key Laboratory of Energy Storage and Power Battery, College of New Energy, Jingchu University of Technology, Jingmen 448000, China
  2. 2Hubei Key Laboratory of Energy Storage and Power Battery EVE Energy Co., Ltd., Jingmen 448124, China

Abstract

Developing low-cost and high-efficiency nonprecious electrocatalysts for the hydrogen evolution reaction (HER) to replace platinum (Pt)-based electrocatalysts is highly desirable for industrial water electrolysis. Nevertheless, the rational design and facile fabrication of an efficient nonprecious HER electrocatalyst is still a huge challenge. Herein, a series of nickel/carbon materials (Ni@C) nanocomposites have been successfully prepared and characterized. In the synthesis of Ni@C samples, the good conductivity of carbon materials can accelerate interfacial charge transfer and thus promote electrocatalytic HER performance, while the component ratio between Ni and C can be adjusted by tuning the mass of carbon precursor. Among all Ni@C samples, the as-prepared [email protected] exhibits excellent electrocatalytic HER performance and long-time stability in an alkaline electrolyte. The optimized [email protected] exhibits outstanding electrocatalytic HER performance with a low overpotential of 134 mV at the current density of −10 mA cm−2 and good durability. The superior electrocatalytic HER performance of the [email protected] sample originates from the large specific surface area and mesoporous structure of C materials. This research offers a new approach for fabricating and developing economical and efficient transitional metal-based HER electrocatalysts for potential industrial water splitting.

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BibTeX
@article{ke2026onestep,
  title = {{One-Step Molten Salt Assistant Synthesis of Ni Nanoparticles Incorporated on Carbon Materials as Hydrogen Evolution Electrocatalyst}},
  author = {Heng Ke and Yunshan Ding and Xinyi Liao and Jianpeng Tan and Luyao Hou and Liangzhe Chen and Wentao Tang and Youbing Zhang and Jun Wang and Yaya Xie},
  journal = {Catalysts},
  year = {2026},
  month = oct,
  doi = {10.3390/catal16110958},
  url = {https://www.mdpi.com/2073-4344/16/11/958},
  note = {CC BY 4.0},
}
RIS
TY  - JOUR
TI  - One-Step Molten Salt Assistant Synthesis of Ni Nanoparticles Incorporated on Carbon Materials as Hydrogen Evolution Electrocatalyst
AU  - Heng Ke
AU  - Yunshan Ding
AU  - Xinyi Liao
AU  - Jianpeng Tan
AU  - Luyao Hou
AU  - Liangzhe Chen
AU  - Wentao Tang
AU  - Youbing Zhang
AU  - Jun Wang
AU  - Yaya Xie
PY  - 2026
DA  - 2026/10/28
JO  - Catalysts
DO  - 10.3390/catal16110958
UR  - https://www.mdpi.com/2073-4344/16/11/958
AB  - Developing low-cost and high-efficiency nonprecious electrocatalysts for the hydrogen evolution reaction (HER) to replace platinum (Pt)-based electrocatalysts is highly desirable for industrial water electrolysis. Nevertheless, the rational design and facile fabrication of an efficient nonprecious HER electrocatalyst is still a huge challenge. Herein, a series of nickel/carbon materials (Ni@C) nanocomposites have been successfully prepared and characterized. In the synthesis of Ni@C samples, the good conductivity of carbon materials can accelerate interfacial charge transfer and thus promote electrocatalytic HER performance, while the component ratio between Ni and C can be adjusted by tuning the mass of carbon precursor. Among all Ni@C samples, the as-prepared [email protected] exhibits excellent electrocatalytic HER performance and long-time stability in an alkaline electrolyte. The optimized [email protected] exhibits outstanding electrocatalytic HER performance with a low overpotential of 134 mV at the current density of −10 mA cm−2 and good durability. The superior electrocatalytic HER performance of the [email protected] sample originates from the large specific surface area and mesoporous structure of C materials. This research offers a new approach for fabricating and developing economical and efficient transitional metal-based HER electrocatalysts for potential industrial water splitting.
SN  - 2073-4344
ER  -