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Peer-reviewedCC BYOrganic letters

Nickel-Catalyzed Carbonylative Synthesis of 1,6-Diketones from Cycloalkylsilyl Peroxides and Arylboronic Acids.

  • Jiacong Ma1
  • Zilin Huang1
  • Hongyi Huang1
  • Xinxin Qi1
  • Xiao-Feng Wu2,3
  1. 1School of Chemistry and Chemical Engineering, Key Laboratory of Surface & Interface Science of Polymer Materials of Zhejiang Province, Zhejiang Sci-Tech University, Hangzhou, Zhejiang310018, People's Republic of China.
  2. 2Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, Liaoning116023, China.
  3. 3Leibniz-Institut für Katalyse e.V., Albert-Einstein-Straße 29a, 18059Rostock, Germany.
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Abstract

A nickel catalyst has been successfully explored for the carbonylative synthesis of 1,6-diketones from cycloalkylsilyl peroxides and arylboronic acids. Under nickel catalysis, using cycloalkylsilyl peroxides as carbonyl-containing alkyl radicals and formic acid as a safe CO source, the protocol affords a variety of 1,6-diketones in good yields, in general with promising functional group tolerance. This transformation represents a general and complementary strategy for the construction of valuable 1,6-diketones.

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Cite

BibTeXRIS
BibTeX
@article{ma2026nickelcatalyzed,
  title = {{Nickel-Catalyzed Carbonylative Synthesis of 1,6-Diketones from Cycloalkylsilyl Peroxides and Arylboronic Acids.}},
  author = {Jiacong Ma and Zilin Huang and Hongyi Huang and Xinxin Qi and Xiao-Feng Wu},
  journal = {Organic letters},
  year = {2026},
  month = oct,
  doi = {10.1021/acs.orglett.6c03636},
  url = {https://europepmc.org/article/MED/42917806},
  note = {CC BY},
}
RIS
TY  - JOUR
TI  - Nickel-Catalyzed Carbonylative Synthesis of 1,6-Diketones from Cycloalkylsilyl Peroxides and Arylboronic Acids.
AU  - Jiacong Ma
AU  - Zilin Huang
AU  - Hongyi Huang
AU  - Xinxin Qi
AU  - Xiao-Feng Wu
PY  - 2026
DA  - 2026/10/01
JO  - Organic letters
DO  - 10.1021/acs.orglett.6c03636
UR  - https://europepmc.org/article/MED/42917806
AB  - A nickel catalyst has been successfully explored for the carbonylative synthesis of 1,6-diketones from cycloalkylsilyl peroxides and arylboronic acids. Under nickel catalysis, using cycloalkylsilyl peroxides as carbonyl-containing alkyl radicals and formic acid as a safe CO source, the protocol affords a variety of 1,6-diketones in good yields, in general with promising functional group tolerance. This transformation represents a general and complementary strategy for the construction of valuable 1,6-diketones.
SN  - 1523-7060
SN  - 1523-7052
ER  -