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Peer-reviewedCC BY-NC-ND 4.0Nature Communications

Chiral trions in enantiopure single-wall carbon nanotubes

Abstract

A trion is a charged exciton, which can be observed in many low-dimensional semiconductors. Circular dichroism (CD) of trions was demonstrated based on optical transitions following their spin selection rules, such as spin states of semiconductor quantum dots and valley spin polarization in monolayer two-dimensional materials. However, the configurational CD of trions, which is uniquely caused by chiral structures, has never been observed. In this study, the CD of trions in enantiopure single-wall carbon nanotubes (SWCNTs) is demonstrated. Depending on the right- or left-handedness of the SWCNTs, the sign of the trion CD changes and is the same as that of the original exciton CD. Consequently, chiral trions exist in chiral SWCNTs.

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BibTeX
@article{fujinami2026chiral,
  title = {{Chiral trions in enantiopure single-wall carbon nanotubes}},
  author = {Hiroyuki Fujinami and Satoshi Kusaba and Satoru Konabe and Weilu Gao and Jana Zaumseil and Kazuhiro Yanagi},
  journal = {Nature Communications},
  year = {2026},
  month = sep,
  doi = {10.1038/s41467-026-78073-z},
  url = {https://www.nature.com/articles/s41467-026-78073-z},
  note = {CC BY-NC-ND 4.0},
}
RIS
TY  - JOUR
TI  - Chiral trions in enantiopure single-wall carbon nanotubes
AU  - Hiroyuki Fujinami
AU  - Satoshi Kusaba
AU  - Satoru Konabe
AU  - Weilu Gao
AU  - Jana Zaumseil
AU  - Kazuhiro Yanagi
PY  - 2026
DA  - 2026/09/30
JO  - Nature Communications
DO  - 10.1038/s41467-026-78073-z
UR  - https://www.nature.com/articles/s41467-026-78073-z
AB  - A trion is a charged exciton, which can be observed in many low-dimensional semiconductors. Circular dichroism (CD) of trions was demonstrated based on optical transitions following their spin selection rules, such as spin states of semiconductor quantum dots and valley spin polarization in monolayer two-dimensional materials. However, the configurational CD of trions, which is uniquely caused by chiral structures, has never been observed. In this study, the CD of trions in enantiopure single-wall carbon nanotubes (SWCNTs) is demonstrated. Depending on the right- or left-handedness of the SWCNTs, the sign of the trion CD changes and is the same as that of the original exciton CD. Consequently, chiral trions exist in chiral SWCNTs.
SN  - 2041-1723
ER  -