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Active Self-Consistent Field Theory for Ornstein-Uhlenbeck Polymers

Abstract

We develop an active self-consistent field theory (ASCFT) for studying the steady-state behavior of active Ornstein--Uhlenbeck polymers. Starting from the stochastic equations of motion under the unified colored noise approximation, we derive an effective Hamiltonian that extends the classical polymer field theory to non-equilibrium systems. The resulting free energy functional incorporates both the Flory--Huggins interaction parameter χN and the persistence time τ of the active noise, enabling a unified description of thermodynamic and activity-driven effects. To solve the governing equations, we implement a stable implicit-explicit numerical scheme that handles the fourth-order term induced by activity. Our simulations reveal that increasing activity suppresses microphase separation, with the density modulation amplitude decaying as Δϕ∝ τ−1/2 for large τ. This scaling is independent of copolymer composition and is confirmed by an asymptotic analysis of the free energy functional in the large-τ limit. The ASCFT framework provides a new theoretical tool for predicting and designing the non-equilibrium morphologies of active polymer systems, bridging the gap between traditional self-consistent field theory and active matter physics.

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BibTeX
@misc{huang2026active,
  title = {{Active Self-Consistent Field Theory for Ornstein-Uhlenbeck Polymers}},
  author = {Yuliang Huang and Chun-Lai Ren and Qiyun Tang},
  howpublished = {arXiv},
  year = {2026},
  month = sep,
  doi = {10.48550/arxiv.2609.28124},
  eprint = {2609.28124},
  archivePrefix = {arXiv},
  url = {https://arxiv.org/abs/2609.28124},
}
RIS
TY  - UNPB
TI  - Active Self-Consistent Field Theory for Ornstein-Uhlenbeck Polymers
AU  - Yuliang Huang
AU  - Chun-Lai Ren
AU  - Qiyun Tang
PY  - 2026
DA  - 2026/09/23
PB  - arXiv
DO  - 10.48550/arxiv.2609.28124
UR  - https://arxiv.org/abs/2609.28124
AB  - We develop an active self-consistent field theory (ASCFT) for studying the steady-state behavior of active Ornstein--Uhlenbeck polymers. Starting from the stochastic equations of motion under the unified colored noise approximation, we derive an effective Hamiltonian that extends the classical polymer field theory to non-equilibrium systems. The resulting free energy functional incorporates both the Flory--Huggins interaction parameter χN and the persistence time τ of the active noise, enabling a unified description of thermodynamic and activity-driven effects. To solve the governing equations, we implement a stable implicit-explicit numerical scheme that handles the fourth-order term induced by activity. Our simulations reveal that increasing activity suppresses microphase separation, with the density modulation amplitude decaying as Δϕ∝ τ^−1/2 for large τ. This scaling is independent of copolymer composition and is confirmed by an asymptotic analysis of the free energy functional in the large-τ limit. The ASCFT framework provides a new theoretical tool for predicting and designing the non-equilibrium morphologies of active polymer systems, bridging the gap between traditional self-consistent field theory and active matter physics.
ER  -