Crystal structure and Hirshfeld surface analysis of 2,5-dimethyl-1 H -benzo[ d ]imidazole

Abstract

The title molecule, C 9 H 10 N 2 , exhibits whole-molecule disorder in a 0.849 (4)/0.151 (4) ratio. The bicyclic portion is planar. In the crystal, a layer structure parallel to the ac plane is generated by N—H...N hydrogen bonds and C—H...π(ring) interactions. Hirshfeld surface analysis indicates that the most important contributions to the crystal packing are from H...H, C...H/H...C and N...H/H...N interactions.

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BibTeX

@article{oulhaj2026crystal,
  title = {{Crystal structure and Hirshfeld surface analysis of 2,5-dimethyl-1 H -benzo[ d ]imidazole}},
  author = {Achrafe Oulhaj and Jihad Sebhaoui and Gamal Al Ati and Fares Hezam Al-Ostoot and Joel Mague and El Mokhtar Essassi and Adam Duong and Karim Chkirate},
  journal = {Acta crystallographica Section E : Crystallographic communications [2015-...]},
  year = {2026},
  month = sep,
  doi = {10.1107/s2056989026009072},
  url = {https://u-picardie.hal.science/hal-05786648v1},
  note = {CC BY},
}

RIS

TY  - JOUR
TI  - Crystal structure and Hirshfeld surface analysis of 2,5-dimethyl-1 H -benzo[ d ]imidazole
AU  - Achrafe Oulhaj
AU  - Jihad Sebhaoui
AU  - Gamal Al Ati
AU  - Fares Hezam Al-Ostoot
AU  - Joel Mague
AU  - El Mokhtar Essassi
AU  - Adam Duong
AU  - Karim Chkirate
PY  - 2026
DA  - 2026/09/08
JO  - Acta crystallographica Section E : Crystallographic communications [2015-...]
DO  - 10.1107/s2056989026009072
UR  - https://u-picardie.hal.science/hal-05786648v1
AB  - The title molecule, C 9 H 10 N 2 , exhibits whole-molecule disorder in a 0.849 (4)/0.151 (4) ratio. The bicyclic portion is planar. In the crystal, a layer structure parallel to the ac plane is generated by N—H...N hydrogen bonds and C—H...π(ring) interactions. Hirshfeld surface analysis indicates that the most important contributions to the crystal packing are from H...H, C...H/H...C and N...H/H...N interactions.
SN  - 2056-9890
ER  -

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