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Peer-reviewedCC BYARKIVOC - Online Journal of Organic Chemistry

Synthesis of a trisphenol alkyne, towards clickable tripods for graphene functionalization

Abstract

In the framework of a project aiming at improving the functionalization of graphene used in Single GrapheneField Effect Transistors (SGFET) biosensors, we have developed a synthetic route to access 4,4',4''-(prop-2-yne-1,1,1-triyl)triphenol which is a key intermediate that can be further functionalized with different pyrene feetleading to clickable tripods. An original method for deprotection of benzyl ethers has been used since theclassical hydrogenolysis method led to an undesired compound.

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BibTeX
@article{alhindi2026synthesis,
  title = {{Synthesis of a trisphenol alkyne, towards clickable tripods for graphene functionalization}},
  author = {Mohammad Danish Alhindi and Ahmed Mehdi Debela and Mayleen Scharre and Thomas Alava and Gad Fuks},
  journal = {ARKIVOC - Online Journal of Organic Chemistry},
  year = {2026},
  month = sep,
  doi = {10.24820/ark.5550190.p012.618},
  url = {https://univ-perp.hal.science/hal-05783135v1},
  note = {CC BY},
}
RIS
TY  - JOUR
TI  - Synthesis of a trisphenol alkyne, towards clickable tripods for graphene functionalization
AU  - Mohammad Danish Alhindi
AU  - Ahmed Mehdi Debela
AU  - Mayleen Scharre
AU  - Thomas Alava
AU  - Gad Fuks
PY  - 2026
DA  - 2026/09/16
JO  - ARKIVOC - Online Journal of Organic Chemistry
DO  - 10.24820/ark.5550190.p012.618
UR  - https://univ-perp.hal.science/hal-05783135v1
AB  - In the framework of a project aiming at improving the functionalization of graphene used in Single GrapheneField Effect Transistors (SGFET) biosensors, we have developed a synthetic route to access 4,4',4''-(prop-2-yne-1,1,1-triyl)triphenol which is a key intermediate that can be further functionalized with different pyrene feetleading to clickable tripods. An original method for deprotection of benzyl ethers has been used since theclassical hydrogenolysis method led to an undesired compound.
SN  - 1551-7004
SN  - 1551-7012
ER  -