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PreprintCC BY 4.0arXiv

Evolution from Kitaev to XXZ spin chains via distortion: Application to BaCo2V2O8

Abstract

BaCo2V2O8 is a prototypical spin-orbit-coupled Ising-chain antiferromagnet that provides a unique platform for studying field-induced quantum magnetism. Under a transverse magnetic field, it exhibits unusual magnetic properties, including an anomalous staggered magnetization and a pronounced anisotropy of the critical field with respect to the in-plane field direction. While these phenomena have been attributed phenomenologically to a site-dependent anisotropic g-tensor, a recent microscopic theory has shown that spin-orbit coupling naturally generates bond-dependent Heisenberg, Kitaev, and Γ exchange interactions. Here, we unify these two pictures by extending the microscopic theory to incorporate distortions of the CoO6 octahedra. We show that the distortions not only generate the site-dependent anisotropic g-tensor but also renormalize the staggered exchange interactions through a distortion-induced contribution that partially compensates the Kitaev-derived staggered term. Using point-charge calculations to estimate the g-tensor of BaCo2V2O8, we demonstrate that the strong anisotropy of the critical field originates from the combined effects of the modified exchange interactions and the anisotropic g-tensor. Our work provides a unified microscopic framework for understanding the magnetic anisotropy of spin-orbit-coupled Ising-chain materials.

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BibTeX
@misc{richard2026evolution,
  title = {{Evolution from Kitaev to XXZ spin chains via distortion: Application to BaCo$_2$V$_2$O$_8$}},
  author = {Philip Richard and Mandev Bhullar and Hae-Young Kee},
  howpublished = {arXiv},
  year = {2026},
  month = sep,
  doi = {10.48550/arxiv.2609.01805},
  eprint = {2609.01805},
  archivePrefix = {arXiv},
  url = {https://arxiv.org/abs/2609.01805},
  note = {CC BY 4.0},
}
RIS
TY  - UNPB
TI  - Evolution from Kitaev to XXZ spin chains via distortion: Application to BaCo_2V_2O_8
AU  - Philip Richard
AU  - Mandev Bhullar
AU  - Hae-Young Kee
PY  - 2026
DA  - 2026/09/01
PB  - arXiv
DO  - 10.48550/arxiv.2609.01805
UR  - https://arxiv.org/abs/2609.01805
AB  - BaCo_2V_2O_8 is a prototypical spin-orbit-coupled Ising-chain antiferromagnet that provides a unique platform for studying field-induced quantum magnetism. Under a transverse magnetic field, it exhibits unusual magnetic properties, including an anomalous staggered magnetization and a pronounced anisotropy of the critical field with respect to the in-plane field direction. While these phenomena have been attributed phenomenologically to a site-dependent anisotropic g-tensor, a recent microscopic theory has shown that spin-orbit coupling naturally generates bond-dependent Heisenberg, Kitaev, and Γ exchange interactions. Here, we unify these two pictures by extending the microscopic theory to incorporate distortions of the CoO_6 octahedra. We show that the distortions not only generate the site-dependent anisotropic g-tensor but also renormalize the staggered exchange interactions through a distortion-induced contribution that partially compensates the Kitaev-derived staggered term. Using point-charge calculations to estimate the g-tensor of BaCo_2V_2O_8, we demonstrate that the strong anisotropy of the critical field originates from the combined effects of the modified exchange interactions and the anisotropic g-tensor. Our work provides a unified microscopic framework for understanding the magnetic anisotropy of spin-orbit-coupled Ising-chain materials.
ER  -