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Peer-reviewedCC BYIUCrData

Bis[(2-bromo-phen-yl)di-cyclo-hexyl-phosphane-κ²Br,P]di-chlorido-ruthenium(II) methanol 1.6-solvate.

  • Monsuru T Kelani1
  • Eric C Hosten2
  • Alfred Muller1
  • Koop Lammertsma1
  1. 1Department of Chemical Sciences, University of Johannesburg, Auckland Park, Johannesburg 2006, South Africa.
  2. 2Department of Chemistry, Nelson Mandela University, Summerstrand, Port Elizabeth 6001, South Africa.
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Abstract

The title compound, [RuCl2(C18H26BrP)2]·1.6CH3OH, crystallizes in the monoclinic space group P2/n with two and a half mol-ecules plus four mol-ecules of methanol solvent in the asymmetric unit (Z' = 5/2, Z = 10). Distortion of the octahedral coordination environment results in the slight variation of bond lengths and bond angles from ideal values. The crystal packing is reinforced by classical hydrogen bonding, O-H⋯X (where X = O or Cl) and non-classical hydrogen bonding inter-actions such as C-H⋯Cl.

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Cite

BibTeXRIS
BibTeX
@article{kelani2026bis2bromophenyldicyclohexylphosphaneκ²brpdichloridorutheniumii,
  title = {{Bis[(2-bromo-phen-yl)di-cyclo-hexyl-phosphane-κ²Br,P]di-chlorido-ruthenium(II) methanol 1.6-solvate.}},
  author = {Monsuru T Kelani and Eric C Hosten and Alfred Muller and Koop Lammertsma},
  journal = {IUCrData},
  year = {2026},
  month = sep,
  doi = {10.1107/s2414314626010862},
  url = {https://europepmc.org/article/MED/42997247},
  note = {CC BY},
}
RIS
TY  - JOUR
TI  - Bis[(2-bromo-phen-yl)di-cyclo-hexyl-phosphane-κ²Br,P]di-chlorido-ruthenium(II) methanol 1.6-solvate.
AU  - Monsuru T Kelani
AU  - Eric C Hosten
AU  - Alfred Muller
AU  - Koop Lammertsma
PY  - 2026
DA  - 2026/09/01
JO  - IUCrData
DO  - 10.1107/s2414314626010862
UR  - https://europepmc.org/article/MED/42997247
AB  - The title compound, [RuCl2(C18H26BrP)2]·1.6CH3OH, crystallizes in the monoclinic space group P2/n with two and a half mol-ecules plus four mol-ecules of methanol solvent in the asymmetric unit (Z' = 5/2, Z = 10). Distortion of the octahedral coordination environment results in the slight variation of bond lengths and bond angles from ideal values. The crystal packing is reinforced by classical hydrogen bonding, O-H⋯X (where X = O or Cl) and non-classical hydrogen bonding inter-actions such as C-H⋯Cl.
SN  - 2414-3146
ER  -