24-hr Solid-State Power Generation with Self-Adaptive Tunable Radiative Coatings
Abstract
Day-night solid-state power generation is experimentally demonstrated with thermoelectric generators integrated with a tunable radiative coating, which switches between a selective solar absorber during daytime and a radiative cooler during nighttime by temperature without any external control. The self-adaptive radiative coating is carefully designed with thermochromic VO2 thin film on heavily doped silicon substrate along with a phase-shifting silicon spacer in between, whose physical mechanism is elucidated. The fabricated coating exhibits a high solar absorptivity of 0.90 and a low infrared emissivity of 0.23 during daytime, and a high emissivity of 0.85 at night, resulting in large emissivity change of 0.62 within the atmospheric transparency window upon metal-to-insulator phase transition. From outdoor tests in a high vacuum apparatus, the tunable radiative coating in 35-mm squared size achieves 1.64 W/m2 power generation around noon time from a stack of commercial thermoelectric modules of 15 mm squared, which is 32% more from that with a black absorber. At night, it produces 26 mW/m2 power, outperforming the black emitter by 63%. Even exposed the ambient with convective loss, the 2-inch-round tunable coating generates power of 0.48 W/m2 at noon time, 14% more than the black absorber of the same size. The tunable radiative coating covered thermoelectric modules produces open circuit voltages from 433 mV to -62 mV in vacuum and from 300 mV to -51 mV in ambient through 24-hr continuous outdoor tests.
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BibTeX
@misc{araki202624hr,
title = {{24-hr Solid-State Power Generation with Self-Adaptive Tunable Radiative Coatings}},
author = {Ken Araki and Liping Wang},
howpublished = {arXiv},
year = {2026},
month = sep,
doi = {10.48550/arxiv.2609.36983},
eprint = {2609.36983},
archivePrefix = {arXiv},
url = {https://arxiv.org/abs/2609.36983},
note = {CC BY 4.0},
}
RIS
TY - UNPB
TI - 24-hr Solid-State Power Generation with Self-Adaptive Tunable Radiative Coatings
AU - Ken Araki
AU - Liping Wang
PY - 2026
DA - 2026/09/29
PB - arXiv
DO - 10.48550/arxiv.2609.36983
UR - https://arxiv.org/abs/2609.36983
AB - Day-night solid-state power generation is experimentally demonstrated with thermoelectric generators integrated with a tunable radiative coating, which switches between a selective solar absorber during daytime and a radiative cooler during nighttime by temperature without any external control. The self-adaptive radiative coating is carefully designed with thermochromic VO2 thin film on heavily doped silicon substrate along with a phase-shifting silicon spacer in between, whose physical mechanism is elucidated. The fabricated coating exhibits a high solar absorptivity of 0.90 and a low infrared emissivity of 0.23 during daytime, and a high emissivity of 0.85 at night, resulting in large emissivity change of 0.62 within the atmospheric transparency window upon metal-to-insulator phase transition. From outdoor tests in a high vacuum apparatus, the tunable radiative coating in 35-mm squared size achieves 1.64 W/m2 power generation around noon time from a stack of commercial thermoelectric modules of 15 mm squared, which is 32% more from that with a black absorber. At night, it produces 26 mW/m2 power, outperforming the black emitter by 63%. Even exposed the ambient with convective loss, the 2-inch-round tunable coating generates power of 0.48 W/m2 at noon time, 14% more than the black absorber of the same size. The tunable radiative coating covered thermoelectric modules produces open circuit voltages from 433 mV to -62 mV in vacuum and from 300 mV to -51 mV in ambient through 24-hr continuous outdoor tests.
ER -