Skip to content
DraconiticResearch
Search Sources API
190,839 studies31 sourcesUpdated 4 min ago
Peer-reviewedCC BY-NC 4.0Chemistry (Weinheim an Der Bergstrasse, Germany)

Isolable ArInH2: Double Hydroindation Agent

  • Adam Hochmal1
  • Zdeňka Růžičková1
  • Aleš Růžička1
  • Roman Jambor1
  • Milan Erben1
  • Libor Dostál1
  1. 1Department of General and Inorganic Chemistry Faculty of Chemical Technology University of Pardubice Pardubice Czech Republic
Read full textDOICite

Abstract

The reaction of the P,C,P‐pincer indium(III) chloride ArInCl2 with 2 eq. of K[BEt3H] provided crystalline monomeric indane ArInH2 (1) (Ar = 2,6‐(tBu2PO)2C6H3) bearing two terminal In─H bonds. Indane 1 is a multitalented reagent that serves as a reductant toward dichalcogenides (PhE)2 giving ArIn(EPh)2 (2E, E = S, Se, Te) or a hydride source in reaction with 4‐CF3‐C6H4OH that gives mono‐ or disubstituted indium phenolates ArIn(H)(4‐CF3‐C6H4O) (3), ArIn(4‐CF3‐C6H4O)2 (4) depending on stoichiometry. Most importantly, 1 is an unprecedented double hydroindation agent, as illustrated by its reactions with aldehydes 4‐R‐C6H4CHO (R = OMe, CF3, F) yielding ArIn(4‐R‐C6H4CH2O)2 (5R) or ketene Ph2C═C═O providing ArIn(Ph2C═CH─O)2 (6).

Related

  1. Isolable silyl- and germyl-thioketones dearomatize their own benzene rings at room temperature
    Ryosuke Masuda, Taisei Kuroki, Takumu Saito +1
    ChemRxivPreprintLicence not statedGeneral chemistryChemRxiv
  2. Cyclic ester insertion into a bismuth–amide bond: isolable molecular models for ROP initiation
    Gabija Navickaite, Louis J. Morris, Alexander Evans +2
    Chemical communications (Cambridge, England)Peer-reviewedCC BYFull textOrganic chemistryEurope PMC
  3. Isolable C‐Phosphonio‐Boratavinyl Anion
    Huihui Xu, Aurora Rodríguez‐álvarez, Md Jabed Hossain +5
    Angewandte Chemie International EditionPeer-reviewedCC BY-NC-ND 4.0Full textInorganic & organometallic chemistryHAL
  4. An Isolable Selenocysteine Selenenyl Iodide Connects Deiodination, Active-Site Regeneration, and Inhibition in Iodothyronine Deiodinase Models
    Ryosuke Masuda, Satoru Kuwano, Kei Goto
    JACS AuPeer-reviewedCC BY-NC-ND 4.0Full textGeneral chemistryCrossref
  5. RxnScout: Deploying a Vision-Language Agent for Nickel-Catalyzed C-Glycosylation Condition Optimization
    Yubo Hou, Mingyue Wu, Balamurugan Ramalingam +2
    ChemRxivPreprintLicence not statedGeneral chemistryChemRxiv

Cite

BibTeXRIS
BibTeX
@article{hochmal2026isolable,
  title = {{Isolable ArInH2: Double Hydroindation Agent}},
  author = {Adam Hochmal and Zdeňka Růžičková and Aleš Růžička and Roman Jambor and Milan Erben and Libor Dostál},
  journal = {Chemistry (Weinheim an Der Bergstrasse, Germany)},
  year = {2026},
  month = aug,
  doi = {10.1002/chem.71528},
  url = {https://doi.org/10.1002/chem.71528},
  note = {CC BY-NC 4.0},
}
RIS
TY  - JOUR
TI  - Isolable ArInH2: Double Hydroindation Agent
AU  - Adam Hochmal
AU  - Zdeňka Růžičková
AU  - Aleš Růžička
AU  - Roman Jambor
AU  - Milan Erben
AU  - Libor Dostál
PY  - 2026
DA  - 2026/08/03
JO  - Chemistry (Weinheim an Der Bergstrasse, Germany)
DO  - 10.1002/chem.71528
UR  - https://doi.org/10.1002/chem.71528
AB  - The reaction of the P,C,P‐pincer indium(III) chloride ArInCl2 with 2 eq. of K[BEt3H] provided crystalline monomeric indane ArInH2 (1) (Ar = 2,6‐(tBu2PO)2C6H3) bearing two terminal In─H bonds. Indane 1 is a multitalented reagent that serves as a reductant toward dichalcogenides (PhE)2 giving ArIn(EPh)2 (2E, E = S, Se, Te) or a hydride source in reaction with 4‐CF3‐C6H4OH that gives mono‐ or disubstituted indium phenolates ArIn(H)(4‐CF3‐C6H4O) (3), ArIn(4‐CF3‐C6H4O)2 (4) depending on stoichiometry. Most importantly, 1 is an unprecedented double hydroindation agent, as illustrated by its reactions with aldehydes 4‐R‐C6H4CHO (R = OMe, CF3, F) yielding ArIn(4‐R‐C6H4CH2O)2 (5R) or ketene Ph2C═C═O providing ArIn(Ph2C═CH─O)2 (6).
SN  - 0947-6539
SN  - 1521-3765
ER  -