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PreprintCC BY-NC-NDECSarXiv

High-Pressure Characteristics of a Low-Ir-Loading PEM Water Electrolysis MEA

Abstract

The market share of green hydrogen produced by water electrolysis is rising and the first commercial applications of larger electrolysis systems (>10 MW) are being commissioned. The high iridium use of proton exchange membrane water electrolysis technology can hinder large scale application and requires next-generation low-iridium membrane-electrode assemblies (MEA). It is key that these materials show good durability under industrial conditions, of which high pressure (≥ 3MPa) is a key parameter. For that reason, we have evaluated the performance and durability characteristics of Toshiba’s low-iridium MEA (0.15 mg/cm2 iridium) under high pressure and pressure cycling conditions. These characteristics were negatively influenced by PTL deformation upon pressurization. The negative effects could be successfully mitigated via either the use of thicker PTLs or optimal flow field designs. This study shows that high pressure induced deformation of the PTL is a key factor for degradation and how this can successfully be addressed for the low-iridium Toshiba MEA.

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BibTeX
@misc{dijk2026highpressure,
  title = {{High-Pressure Characteristics of a Low-Ir-Loading PEM Water Electrolysis MEA}},
  author = {Bas van Dijk and Sara Fabrizio and Jochen Löffler and Takechi Nakamoto and Akihiko Ono and Zhengyang Sun and Norihiro Yoshinaga and Kazuto Hasebe and Shoichi Hidai},
  howpublished = {ECSarXiv},
  year = {2026},
  month = oct,
  doi = {10.1149/osf.io/5n9cq_v1},
  url = {https://osf.io/preprints/ecsarxiv/5n9cq_v1/},
  note = {CC BY-NC-ND},
}
RIS
TY  - UNPB
TI  - High-Pressure Characteristics of a Low-Ir-Loading PEM Water Electrolysis MEA
AU  - Bas van Dijk
AU  - Sara Fabrizio
AU  - Jochen Löffler
AU  - Takechi Nakamoto
AU  - Akihiko Ono
AU  - Zhengyang Sun
AU  - Norihiro Yoshinaga
AU  - Kazuto Hasebe
AU  - Shoichi Hidai
PY  - 2026
DA  - 2026/10/28
PB  - ECSarXiv
DO  - 10.1149/osf.io/5n9cq_v1
UR  - https://osf.io/preprints/ecsarxiv/5n9cq_v1/
AB  - The market share of green hydrogen produced by water electrolysis is rising and the first commercial applications of larger electrolysis systems (>10 MW) are being commissioned. The high iridium use of proton exchange membrane water electrolysis technology can hinder large scale application and requires next-generation low-iridium membrane-electrode assemblies (MEA). It is key that these materials show good durability under industrial conditions, of which high pressure (≥ 3MPa) is a key parameter. For that reason, we have evaluated the performance and durability characteristics of Toshiba’s low-iridium MEA (0.15 mg/cm2 iridium) under high pressure and pressure cycling conditions. These characteristics were negatively influenced by PTL deformation upon pressurization. The negative effects could be successfully mitigated via either the use of thicker PTLs or optimal flow field designs. This study shows that high pressure induced deformation of the PTL is a key factor for degradation and how this can successfully be addressed for the low-iridium Toshiba MEA.
ER  -