Supramolecular Metallohydrogels of Fe(III) and Zn(II) with 3-Aminopropan-1-ol as Low Molecular Weight Hydrogelator: Unveiling Self-healing activity, rheological dynamics, and stimuli-sensitivity
Abstract
Two different metallohydrogels of Fe(III) and Zn(II) have been synthesized through the use of low molecular gelator and water as a polar protic fluid medium, encapsulated in distinct metallohydrogel networks. 3-Aminopropan-1-ol is executed as the potential LMWG for achieving non-covalent interaction-guided supramolecular soft -flexible scaffold formation. The mechanical stability and the flexible-features of different metallohydrgel have been explored through exhaustive rheological experimental studies covering shear strain sweep studies, angular frequency sweep investigations, and time sweep based experiments. The rheo-reversible dynamics of both metallohydrogels are examined through current attempts. The self-healing features of different metallohydrogels have been explored. The expression of distinct metallohydrogels under the impacts of diverse externally added stimuli has been thoroughly explored through the work. In a comparative vision the mechanical stability and stimuli effects, the Zn(II) metallohydrogel showed more predominant effect.
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BibTeX
@misc{dolai2026supramolecular,
title = {{Supramolecular Metallohydrogels of Fe(III) and Zn(II) with 3-Aminopropan-1-ol as Low Molecular Weight Hydrogelator: Unveiling Self-healing activity, rheological dynamics, and stimuli-sensitivity}},
author = {Tripti Dolai and Subhasish Ghosh and Suresh Kumar Yatirajula and Biswajit Dey},
howpublished = {ChemRxiv},
year = {2026},
month = sep,
doi = {10.26434/chemrxiv.15008423/v1},
url = {https://chemrxiv.org/doi/full/10.26434/chemrxiv.15008423/v1},
note = {CC BY},
}
RIS
TY - UNPB
TI - Supramolecular Metallohydrogels of Fe(III) and Zn(II) with 3-Aminopropan-1-ol as Low Molecular Weight Hydrogelator: Unveiling Self-healing activity, rheological dynamics, and stimuli-sensitivity
AU - Tripti Dolai
AU - Subhasish Ghosh
AU - Suresh Kumar Yatirajula
AU - Biswajit Dey
PY - 2026
DA - 2026/09/07
PB - ChemRxiv
DO - 10.26434/chemrxiv.15008423/v1
UR - https://chemrxiv.org/doi/full/10.26434/chemrxiv.15008423/v1
AB - Two different metallohydrogels of Fe(III) and Zn(II) have been synthesized through the use of low molecular gelator and water as a polar protic fluid medium, encapsulated in distinct metallohydrogel networks. 3-Aminopropan-1-ol is executed as the potential LMWG for achieving non-covalent interaction-guided supramolecular soft -flexible scaffold formation. The mechanical stability and the flexible-features of different metallohydrgel have been explored through exhaustive rheological experimental studies covering shear strain sweep studies, angular frequency sweep investigations, and time sweep based experiments. The rheo-reversible dynamics of both metallohydrogels are examined through current attempts. The self-healing features of different metallohydrogels have been explored. The expression of distinct metallohydrogels under the impacts of diverse externally added stimuli has been thoroughly explored through the work. In a comparative vision the mechanical stability and stimuli effects, the Zn(II) metallohydrogel showed more predominant effect.
ER -