Skip to content
DraconiticResearch
Search Sources API
197,768 studies31 sourcesUpdated 59 min ago
PreprintarXiv licencearXiv

Khinchin's ergodicity and typicality in statistical mechanics

Abstract

The formulation of statistical mechanics in terms of ensembles, originally proposed by Gibbs, has proved to be extremely effective in describing the equilibrium state of many-particle systems, in the most diverse contexts (critical phenomena, quantum mechanics, biophysics, just to mention a few). The reasons of this success are still debated, and the connection between dynamics and probability in large systems remains somehow elusive. Indeed, in order to derive the main results of equilibrium statistical mechanics, strong assumptions on the ergodicity of the dynamics are usually required. Nonetheless, empirical observations seem to suggest that the predictions of the theory hold true even when such assumptions are not verified. In this paper we reconsider the point of view put forward by Khinchin, stating that the only relevant ingredients for the validity of statistical mechanics are the large number of degrees of freedom in the system and the choice of extensive observables, irrespectively of the details of the microscopic dynamics. In particular, the presence of dynamical chaos is not required. To this aim, we discuss some analytical and numerical results on a couple of classical integrable systems, the harmonic chain and the Toda model, showing that many important features predicted by equilibrium statistical mechanics, as for instance Maxwell-Boltzmann distribution, are found even in absence of chaos.

Versions

Related

  1. On the Statistical Mechanics of Attention
    Jerry Yao-Chieh Hu, Yu-An Chen, Maojiang Su +1
    arXivPreprintCC BY-NC-SA 4.0Full textStatisticsCondensed matterarXiv
  2. Statistical mechanics of spontaneous behavior
    Daniel Y. Takahashi, Ahmed El Hady
    arXivPreprintCC BY 4.0Full textNeuroscienceBiological & medical physicsarXiv
  3. On the relaxation problem in statistical mechanics
    Giuseppe Del Vecchio Del Vecchio
    arXivPreprintCC BY 4.0Full textMathematical physicsQuantum physics & quantum informationarXiv
  4. A polynomial-time classical sampler for noisy quantum circuits from statistical mechanics
    Jon Nelson, Joel Rajakumar, Chao Yin +2
    arXivPreprintCC BY 4.0Full textQuantum physics & quantum informationarXiv
  5. A kinetic model of electron transfer at the electrode-electrolyte interface: Statistical mechanics and electrochemical aspects
    Diego Veloza-Diaz, Robinson Cortes-Huerto, Pietro Ballone +1
    arXivPreprintCC BY-NC-ND 4.0Full textPhysical chemistryStatistical & nonlinear physicsarXiv
BibTeX
@misc{lucente2026khinchins,
  title = {{Khinchin's ergodicity and typicality in statistical mechanics}},
  author = {Dario Lucente and Marco Baldovin and Giacomo Gradenigo and Angelo Vulpiani},
  howpublished = {arXiv},
  year = {2026},
  month = sep,
  doi = {10.48550/arxiv.2609.20433},
  eprint = {2609.20433},
  archivePrefix = {arXiv},
  url = {https://arxiv.org/abs/2609.20433},
}
RIS
TY  - UNPB
TI  - Khinchin's ergodicity and typicality in statistical mechanics
AU  - Dario Lucente
AU  - Marco Baldovin
AU  - Giacomo Gradenigo
AU  - Angelo Vulpiani
PY  - 2026
DA  - 2026/09/17
PB  - arXiv
DO  - 10.48550/arxiv.2609.20433
UR  - https://arxiv.org/abs/2609.20433
AB  - The formulation of statistical mechanics in terms of ensembles, originally proposed by Gibbs, has proved to be extremely effective in describing the equilibrium state of many-particle systems, in the most diverse contexts (critical phenomena, quantum mechanics, biophysics, just to mention a few). The reasons of this success are still debated, and the connection between dynamics and probability in large systems remains somehow elusive. Indeed, in order to derive the main results of equilibrium statistical mechanics, strong assumptions on the ergodicity of the dynamics are usually required. Nonetheless, empirical observations seem to suggest that the predictions of the theory hold true even when such assumptions are not verified. In this paper we reconsider the point of view put forward by Khinchin, stating that the only relevant ingredients for the validity of statistical mechanics are the large number of degrees of freedom in the system and the choice of extensive observables, irrespectively of the details of the microscopic dynamics. In particular, the presence of dynamical chaos is not required. To this aim, we discuss some analytical and numerical results on a couple of classical integrable systems, the harmonic chain and the Toda model, showing that many important features predicted by equilibrium statistical mechanics, as for instance Maxwell-Boltzmann distribution, are found even in absence of chaos.
ER  -