Skip to content
DraconiticResearch
Search Sources API
203,234 studies31 sourcesUpdated 55 min ago
PreprintCC BYChemRxiv

trans -Rich Skeletal Transformation of a Cross-Conjugated Polymer via 1,4-Selective Hydrothiolation

  • Yoichiro Eriguchi1,2,3
  • Masayuki Munemoto2
  • Yuichiro Tokoro2
  • Shin-ichi Yamamoto2
  • Kosuke Sato3,4
  • Shinsuke Inagi3
  • Toshio Koizumi2
4 affiliations
  1. 1Japan Ground Self-Defense Force, Ichigaya Garrison, 5-1 Ichigaya Honmura-cho, Shinjuku-ku, Tokyo, Japan, 162-8802
  2. 2Department of Applied Chemistry, National Defense Academy, 1-10-20 Hashirimizu, Yokosuka, Japan, 239-8686
  3. 3School of Materials and Chemical Technology, Institute of Science Tokyo, 4259 Nagatsuta-cho, Midori-ku, Yokohama, Japan, 226-8501
  4. 4Graduate School of Informatics and Engineering, University of Electro-Communications, 1-5-1 Chofugaoka, Chofu, Tokyo, Japan, 182-8585
Open at sourcePDFDOICite

Abstract

Previous skeletal transformations of cross-conjugated polymers into linear-conjugated structures have been limited to methods involving cyclization, which form only a cis structure on the main chain. In this study, cross-conjugated polymer containing 2,3-linked 1,3-butadiene was successfully converted into a linear-conjugated polymer with cis / trans -isomeric main chains via 1,4-selective hydrothiolation, achieving up to 71% trans -selectivity. In addition, the factors influencing the regio- and stereoselectivities were examined using density functional theory calculations.

Related

  1. Monodisperse Polymer Optical Microresonators as a Versatile Platform for Protein-Conjugated Biocompatible Optical Probes
    Honoka Seki, Kariana K. Dewi, Tomoyuki Tsujimoto +5
    ACS omegaPeer-reviewedCC BY-NC-NDFull textGeneral chemistryEurope PMC
  2. Intramolecular Long-Range Photoinduced Electron Transfer Using π-Way of a Step-π-Conjugated Polymer
    Daisuke Kitayama, Kazuki Takeuchi, Akari Terada +3
    ACS OmegaPeer-reviewedCC BY-NC-ND 4.0Full textPhysical chemistryCrossrefEurope PMCEurope PMCPMC
  3. Mixed Ionic–Electronic Memory in a Conjugated Polymer Composite for Retrospective Optical Event Reconstruction
    Md Al Raihan, Tian Xia, Michael S. Freund
    ChemRxivPreprintCC BY-NC-NDFull textMaterials & polymersChemRxiv
  4. Synthesis and crystal structure of a one-dimensional Hg(II) coordination polymer with two distinct metal centers and its selective fluorescent sensing of Ni²⁺
    Zohreh Derikvand, Ameneh Jahani Chegeni
    Scientific ReportsPeer-reviewedCC BY-NC-ND 4.0Full textInorganic & organometallic chemistryCrossref
  5. A Robust π-Conjugated Radical Cocrystal
    Han Han, Lei Fang
    ACS Central SciencePeer-reviewedCC BY 4.0Full textPhysical chemistryCrossref

Cite

BibTeXRIS
BibTeX
@misc{eriguchi2026trans,
  title = {{trans -Rich Skeletal Transformation of a Cross-Conjugated Polymer via 1,4-Selective Hydrothiolation}},
  author = {Yoichiro Eriguchi and Masayuki Munemoto and Yuichiro Tokoro and Shin-ichi Yamamoto and Kosuke Sato and Shinsuke Inagi and Toshio Koizumi},
  howpublished = {ChemRxiv},
  year = {2026},
  month = oct,
  doi = {10.26434/chemrxiv.15011120/v1},
  url = {https://chemrxiv.org/doi/full/10.26434/chemrxiv.15011120/v1},
  note = {CC BY},
}
RIS
TY  - UNPB
TI  - trans -Rich Skeletal Transformation of a Cross-Conjugated Polymer via 1,4-Selective Hydrothiolation
AU  - Yoichiro Eriguchi
AU  - Masayuki Munemoto
AU  - Yuichiro Tokoro
AU  - Shin-ichi Yamamoto
AU  - Kosuke Sato
AU  - Shinsuke Inagi
AU  - Toshio Koizumi
PY  - 2026
DA  - 2026/10/27
PB  - ChemRxiv
DO  - 10.26434/chemrxiv.15011120/v1
UR  - https://chemrxiv.org/doi/full/10.26434/chemrxiv.15011120/v1
AB  - Previous skeletal transformations of cross-conjugated polymers into linear-conjugated structures have been limited to methods involving cyclization, which form only a cis structure on the main chain. In this study, cross-conjugated polymer containing 2,3-linked 1,3-butadiene was successfully converted into a linear-conjugated polymer with cis / trans -isomeric main chains via 1,4-selective hydrothiolation, achieving up to 71% trans -selectivity. In addition, the factors influencing the regio- and stereoselectivities were examined using density functional theory calculations.
ER  -