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PreprintCC BYChemRxiv

Supramolecular Preorganisation Enables Reversible Solid-state Photopolymerisation

  • Antara Reja
  • Bart W. L. van den Bersselaar
  • Drishya Elizebath
  • Nicolas Daub
  • Iván Marín
  • Bas de Waal
  • Lisa Cattenstart
  • Ghislaine Vantomme
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Abstract

Supramolecular preorganisation enables reversible solid-state photopolymerisation in an oligo(phenylenevinylene)-siloxane material. Photopolymerisation proceeds quantitatively in the ordered state but reaches only ~7% conversion in the disordered melt. Polymerisation disrupts columnar order and alters optical and local-current responses, while thermal depolymerisation largely restores the initial molecular and supramolecular state.

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Cite

BibTeXRIS
BibTeX
@misc{reja2026supramolecular,
  title = {{Supramolecular Preorganisation Enables Reversible Solid-state Photopolymerisation}},
  author = {Antara Reja and Bart W. L. van den Bersselaar and Drishya Elizebath and Nicolas Daub and Iván Marín and Bas de Waal and Lisa Cattenstart and Ghislaine Vantomme},
  howpublished = {ChemRxiv},
  year = {2026},
  month = oct,
  doi = {10.26434/chemrxiv.15010327/v1},
  url = {https://chemrxiv.org/doi/full/10.26434/chemrxiv.15010327/v1},
  note = {CC BY},
}
RIS
TY  - UNPB
TI  - Supramolecular Preorganisation Enables Reversible Solid-state Photopolymerisation
AU  - Antara Reja
AU  - Bart W. L. van den Bersselaar
AU  - Drishya Elizebath
AU  - Nicolas Daub
AU  - Iván Marín
AU  - Bas de Waal
AU  - Lisa Cattenstart
AU  - Ghislaine Vantomme
PY  - 2026
DA  - 2026/10/13
PB  - ChemRxiv
DO  - 10.26434/chemrxiv.15010327/v1
UR  - https://chemrxiv.org/doi/full/10.26434/chemrxiv.15010327/v1
AB  - Supramolecular preorganisation enables reversible solid-state photopolymerisation in an oligo(phenylenevinylene)-siloxane material. Photopolymerisation proceeds quantitatively in the ordered state but reaches only ~7% conversion in the disordered melt. Polymerisation disrupts columnar order and alters optical and local-current responses, while thermal depolymerisation largely restores the initial molecular and supramolecular state.
ER  -