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Peer-reviewedCC BY-NC-ND 4.0ACS Omega

Performance Evaluation of Lipopeptide-Enhanced Petroleum Sulfonate Binary Flooding System

4 affiliations
  1. 1Northeast Petroleum University , , , ,
  2. 2Northeast Petroleum University, Ministry of Education , , , ,
  3. 3Zhanjiang Branch , , , ,
  4. 4Research Institute of Exploration and Development , , , ,

Abstract

To address the rapid interfacial activity decay and high adsorption loss of conventional chemical flooding under harsh reservoir conditions, this study developed an alkali-free biochemical binary composite system by partially substituting petroleum sulfonate with the biosurfactant lipopeptide (0.15 wt % petroleum sulfonate + 0.15 wt % lipopeptide + 1400 mg/L HPAM). Systematic thermal aging, emulsification, dynamic antiadsorption, and core flooding evaluations revealed distinct performance enhancements over the conventional chemical binary system. After 60 days of aging at 45–65 °C, the composite system sustained interfacial tension within the ultralow regime (10–2 mN/m) and exhibited a 20–28 percentage points higher viscosity retention rate, along with a counterintuitive decrease in equilibrium interfacial tension at elevated temperatures. In multicycle dynamic sand contact tests at 55 °C, competitive adsorption and steric/electrostatic shielding by lipopeptides prolonged the antiadsorption lifespan by an additional cycle. In physical core displacement experiments, the biochemical system achieved an incremental oil recovery of 6.1 percentage points over the conventional counterpart. These findings demonstrate that “structural and electrical complementarity” between biosurfactants and synthetic surfactants provides an effective, alkali-free route for chemical flooding in heavy oil reservoirs.

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BibTeX
@article{zhang2026performance,
  title = {{Performance Evaluation of Lipopeptide-Enhanced Petroleum Sulfonate Binary Flooding System}},
  author = {Yunbao Zhang and Qianqiao Gao and Song Ge and Pengfei Cheng and Fuhao Zhen and Xudong Tang and Xinyue Cao and Ziyang Wang and Guoli Liu and Mengqi Li and Rui Hu},
  journal = {ACS Omega},
  year = {2026},
  month = oct,
  doi = {10.1021/acsomega.6c09414},
  url = {https://pubs.acs.org/acsodf/article/doi/10.1021/acsomega.6c09414/5455647/Performance-Evaluation-of-Lipopeptide-Enhanced},
  note = {CC BY-NC-ND 4.0},
}
RIS
TY  - JOUR
TI  - Performance Evaluation of Lipopeptide-Enhanced Petroleum Sulfonate Binary Flooding System
AU  - Yunbao Zhang
AU  - Qianqiao Gao
AU  - Song Ge
AU  - Pengfei Cheng
AU  - Fuhao Zhen
AU  - Xudong Tang
AU  - Xinyue Cao
AU  - Ziyang Wang
AU  - Guoli Liu
AU  - Mengqi Li
AU  - Rui Hu
PY  - 2026
DA  - 2026/10/01
JO  - ACS Omega
DO  - 10.1021/acsomega.6c09414
UR  - https://pubs.acs.org/acsodf/article/doi/10.1021/acsomega.6c09414/5455647/Performance-Evaluation-of-Lipopeptide-Enhanced
AB  - To address the rapid interfacial activity decay and high adsorption loss of conventional chemical flooding under harsh reservoir conditions, this study developed an alkali-free biochemical binary composite system by partially substituting petroleum sulfonate with the biosurfactant lipopeptide (0.15 wt % petroleum sulfonate + 0.15 wt % lipopeptide + 1400 mg/L HPAM). Systematic thermal aging, emulsification, dynamic antiadsorption, and core flooding evaluations revealed distinct performance enhancements over the conventional chemical binary system. After 60 days of aging at 45–65 °C, the composite system sustained interfacial tension within the ultralow regime (10–2 mN/m) and exhibited a 20–28 percentage points higher viscosity retention rate, along with a counterintuitive decrease in equilibrium interfacial tension at elevated temperatures. In multicycle dynamic sand contact tests at 55 °C, competitive adsorption and steric/electrostatic shielding by lipopeptides prolonged the antiadsorption lifespan by an additional cycle. In physical core displacement experiments, the biochemical system achieved an incremental oil recovery of 6.1 percentage points over the conventional counterpart. These findings demonstrate that “structural and electrical complementarity” between biosurfactants and synthetic surfactants provides an effective, alkali-free route for chemical flooding in heavy oil reservoirs.
SN  - 2470-1343
ER  -