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Peer-reviewedCC BYIUCrData

trans-Di-aqua-bis-(pyridin-2-yl thio-phen-2-yl ketone-κ²N,O)zinc(II) bis-(tetra-fluorido-borate).

  • Barry Westcott1
  • Allen G Oliver2
  1. 1Department of Chemsitry and Biochemistry Central Connecticut State University, 1615 Stanley St New Brtiain CT 06050 USA.
  2. 2Molecular Structure Facility, 149 Stepan Chemistry Hall, Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556, USA.
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Abstract

The title salt, [Zn(C10H7NOS)2(H2O)2](BF4)2, crystallizes isotypically with the CoII analog in the monoclinic space group P21/n. In the com-plex cation, the central ZnII atom (site symmetry 1) has a pseudo-octa-hedral coordination environment with bonding to pyridyl N [2.0624 (18) Å] and carbonyl O [2.1030 (13) Å] atoms from the 2-thienyl 2-pyridyl ketone ligands. The remaining bonds are to water mol-ecules [2.1598 (16) Å], which form an O-H⋯F hy-dro-gen-bonded layer with BF4- counter-ions.

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Cite

BibTeXRIS
BibTeX
@article{westcott2026transdiaquabispyridin2yl,
  title = {{trans-Di-aqua-bis-(pyridin-2-yl thio-phen-2-yl ketone-κ²N,O)zinc(II) bis-(tetra-fluorido-borate).}},
  author = {Barry Westcott and Allen G Oliver},
  journal = {IUCrData},
  year = {2026},
  month = sep,
  doi = {10.1107/s2414314626010369},
  url = {https://europepmc.org/article/MED/42997253},
  note = {CC BY},
}
RIS
TY  - JOUR
TI  - trans-Di-aqua-bis-(pyridin-2-yl thio-phen-2-yl ketone-κ²N,O)zinc(II) bis-(tetra-fluorido-borate).
AU  - Barry Westcott
AU  - Allen G Oliver
PY  - 2026
DA  - 2026/09/01
JO  - IUCrData
DO  - 10.1107/s2414314626010369
UR  - https://europepmc.org/article/MED/42997253
AB  - The title salt, [Zn(C10H7NOS)2(H2O)2](BF4)2, crystallizes isotypically with the CoII analog in the monoclinic space group P21/n. In the com-plex cation, the central ZnII atom (site symmetry 1) has a pseudo-octa-hedral coordination environment with bonding to pyridyl N [2.0624 (18) Å] and carbonyl O [2.1030 (13) Å] atoms from the 2-thienyl 2-pyridyl ketone ligands. The remaining bonds are to water mol-ecules [2.1598 (16) Å], which form an O-H⋯F hy-dro-gen-bonded layer with BF4- counter-ions.
SN  - 2414-3146
ER  -