Crystal structure of 1-[(4-methyl-phen-yl)sulfon-yl]-2-phenyl-azetidine.

Abstract

The crystal structure of 1-[(4-methyl-phen-yl)sulfon-yl]-2-phenyl-azetidine, C16H17NO2S, commonly referred to as 2-phenyl-N-tosyl-azetidine, is reported. There are three close con-tacts stabilizing the supra-molecular structure. Two of the close con-tacts are between one of the O atoms on the sulfonamide moiety and two neighboring C-H bonds from the tolyl ring. The third close con-tact is between the H-C bond of the azetidine and a C atom on the phenyl ring. Distances between the tolyl rings are greater than the standard distance of 5 Å for π-stacking.

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BibTeX

@article{aroche2026crystal,
  title = {{Crystal structure of 1-[(4-methyl-phen-yl)sulfon-yl]-2-phenyl-azetidine.}},
  author = {Berthy J Aroche and Katherine Barraza Hernandez and Zoe Y Marr and S Chantal E Stieber and Taylor A Thane},
  journal = {Acta crystallographica. Section E, Crystallographic communications},
  year = {2026},
  month = oct,
  doi = {10.1107/s2056989026010315},
  url = {https://europepmc.org/article/MED/42997293},
  note = {CC BY},
}

RIS

TY  - JOUR
TI  - Crystal structure of 1-[(4-methyl-phen-yl)sulfon-yl]-2-phenyl-azetidine.
AU  - Berthy J Aroche
AU  - Katherine Barraza Hernandez
AU  - Zoe Y Marr
AU  - S Chantal E Stieber
AU  - Taylor A Thane
PY  - 2026
DA  - 2026/10/11
JO  - Acta crystallographica. Section E, Crystallographic communications
DO  - 10.1107/s2056989026010315
UR  - https://europepmc.org/article/MED/42997293
AB  - The crystal structure of 1-[(4-methyl-phen-yl)sulfon-yl]-2-phenyl-azetidine, C16H17NO2S, commonly referred to as 2-phenyl-N-tosyl-azetidine, is reported. There are three close con-tacts stabilizing the supra-molecular structure. Two of the close con-tacts are between one of the O atoms on the sulfonamide moiety and two neighboring C-H bonds from the tolyl ring. The third close con-tact is between the H-C bond of the azetidine and a C atom on the phenyl ring. Distances between the tolyl rings are greater than the standard distance of 5 Å for π-stacking.
SN  - 2056-9890
ER  -

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