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PreprintCC BY 4.0arXiv

Landau theory applied to antiferroelectric ordering in ferroelectric nematic liquid crystals

Abstract

The polarization and mass density modulation associated with antiferroelectric ordering in two ferroelectric nematic liquid crystals, a prototypical single compound (referred to as DIO) and a commercial mixture (FNLC919), are studied experimentally as a function of temperature. The wavenumber of the polarization modulation, qA, is determined by small angle X-ray diffraction from the weak, accompanying density wave (wavenumber qS = 2qA) using a conventional laboratory source. Combined results for qS and the saturated value of the polarization are analyzed in terms of Landau theory previously developed to describe the para-/antiferro-/ferroelectric sequence of phase transitions in solid ferroelectrics. The analysis of qS indicates that the polarization modulation can be reasonably well approximated by a simple sinusoid in DIO, whereas in FNLC919 a sharp decrease in qS close to the antiferro- to ferroelectric transition indicates development of a soliton-like profile.

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BibTeX
@misc{badu2026landau,
  title = {{Landau theory applied to antiferroelectric ordering in ferroelectric nematic liquid crystals}},
  author = {Manisha Badu and Arjun Ghimire and Milon and Priyanka Kumari and Hari Krishna Bisoyi and Oleg D. Lavrentovich and James Gleeson and Antal Jakli and Samuel Sprunt},
  howpublished = {arXiv},
  year = {2026},
  month = oct,
  doi = {10.48550/arxiv.2605.11413},
  eprint = {2605.11413},
  archivePrefix = {arXiv},
  url = {https://arxiv.org/abs/2605.11413},
  note = {CC BY 4.0},
}
RIS
TY  - UNPB
TI  - Landau theory applied to antiferroelectric ordering in ferroelectric nematic liquid crystals
AU  - Manisha Badu
AU  - Arjun Ghimire
AU  - Milon
AU  - Priyanka Kumari
AU  - Hari Krishna Bisoyi
AU  - Oleg D. Lavrentovich
AU  - James Gleeson
AU  - Antal Jakli
AU  - Samuel Sprunt
PY  - 2026
DA  - 2026/10/17
PB  - arXiv
DO  - 10.48550/arxiv.2605.11413
UR  - https://arxiv.org/abs/2605.11413
AB  - The polarization and mass density modulation associated with antiferroelectric ordering in two ferroelectric nematic liquid crystals, a prototypical single compound (referred to as DIO) and a commercial mixture (FNLC919), are studied experimentally as a function of temperature. The wavenumber of the polarization modulation, qA, is determined by small angle X-ray diffraction from the weak, accompanying density wave (wavenumber qS = 2qA) using a conventional laboratory source. Combined results for qS and the saturated value of the polarization are analyzed in terms of Landau theory previously developed to describe the para-/antiferro-/ferroelectric sequence of phase transitions in solid ferroelectrics. The analysis of qS indicates that the polarization modulation can be reasonably well approximated by a simple sinusoid in DIO, whereas in FNLC919 a sharp decrease in qS close to the antiferro- to ferroelectric transition indicates development of a soliton-like profile.
ER  -