Landau theory applied to antiferroelectric ordering in ferroelectric nematic liquid crystals
Abstract
The polarization and mass density modulation associated with antiferroelectric ordering in two ferroelectric nematic liquid crystals, a prototypical single compound (referred to as DIO) and a commercial mixture (FNLC919), are studied experimentally as a function of temperature. The wavenumber of the polarization modulation, qA, is determined by small angle X-ray diffraction from the weak, accompanying density wave (wavenumber qS = 2qA) using a conventional laboratory source. Combined results for qS and the saturated value of the polarization are analyzed in terms of Landau theory previously developed to describe the para-/antiferro-/ferroelectric sequence of phase transitions in solid ferroelectrics. The analysis of qS indicates that the polarization modulation can be reasonably well approximated by a simple sinusoid in DIO, whereas in FNLC919 a sharp decrease in qS close to the antiferro- to ferroelectric transition indicates development of a soliton-like profile.
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BibTeX
@misc{badu2026landau,
title = {{Landau theory applied to antiferroelectric ordering in ferroelectric nematic liquid crystals}},
author = {Manisha Badu and Arjun Ghimire and Milon and Priyanka Kumari and Hari Krishna Bisoyi and Oleg D. Lavrentovich and James Gleeson and Antal Jakli and Samuel Sprunt},
howpublished = {arXiv},
year = {2026},
month = oct,
doi = {10.48550/arxiv.2605.11413},
eprint = {2605.11413},
archivePrefix = {arXiv},
url = {https://arxiv.org/abs/2605.11413},
note = {CC BY 4.0},
}
RIS
TY - UNPB
TI - Landau theory applied to antiferroelectric ordering in ferroelectric nematic liquid crystals
AU - Manisha Badu
AU - Arjun Ghimire
AU - Milon
AU - Priyanka Kumari
AU - Hari Krishna Bisoyi
AU - Oleg D. Lavrentovich
AU - James Gleeson
AU - Antal Jakli
AU - Samuel Sprunt
PY - 2026
DA - 2026/10/17
PB - arXiv
DO - 10.48550/arxiv.2605.11413
UR - https://arxiv.org/abs/2605.11413
AB - The polarization and mass density modulation associated with antiferroelectric ordering in two ferroelectric nematic liquid crystals, a prototypical single compound (referred to as DIO) and a commercial mixture (FNLC919), are studied experimentally as a function of temperature. The wavenumber of the polarization modulation, qA, is determined by small angle X-ray diffraction from the weak, accompanying density wave (wavenumber qS = 2qA) using a conventional laboratory source. Combined results for qS and the saturated value of the polarization are analyzed in terms of Landau theory previously developed to describe the para-/antiferro-/ferroelectric sequence of phase transitions in solid ferroelectrics. The analysis of qS indicates that the polarization modulation can be reasonably well approximated by a simple sinusoid in DIO, whereas in FNLC919 a sharp decrease in qS close to the antiferro- to ferroelectric transition indicates development of a soliton-like profile.
ER -