A dinuclear silver(I) com-plex of 6-phenyl-2,2':6',2''-terpyridine.
- 1Department of Applied and Materials Chemistry College of Science and Technology Nihon University, 1-8-14 Kanda Surugadai Chiyoda-ku Tokyo 101-8308 Japan.
Abstract
A dinuclear silver(I) com-plex of 6-phenyl-2,2':6',2''-terpyridine, bis-(μ-6-phenyl-2,2':6',2''-terpyridine)-bis-[(tri-fluoro-methane-sulfonato)-silver(I)], [Ag2(C21H15N3)(CF3SO3)2], was obtained by crystallization with silver tri-fluoro-methane-sulfonate and characterized by single-crystal X-ray diffraction. Two symmetry-related terpyridine ligands bridge two AgI ions. The AgI ion has a highly distorted four-coordinate N3O environment com-prising three pyridyl N atoms and one tri-fluoro-methane-sulfonate O atom. The intra-molecular Ag⋯Ag separation of 2.8501 (8) Å is consistent with an argentophilic inter-action. An intra-molecular phen-yl-pyridyl π-π contact is also present. The structure demonstrates that a single phenyl substituent at the 6-position is com-patible with ligand bridging and the formation of a short Ag⋯Ag contact.
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BibTeX
@article{nakaie2026dinuclear,
title = {{A dinuclear silver(I) com-plex of 6-phenyl-2,2':6',2''-terpyridine.}},
author = {Yuto Nakaie and Tomoya Abe and Yosuke Hosoya and Kosuke Sugawa and Joe Otsuki},
journal = {IUCrData},
year = {2026},
month = sep,
doi = {10.1107/s2414314626010436},
url = {https://europepmc.org/article/MED/42997380},
note = {CC BY},
}
RIS
TY - JOUR
TI - A dinuclear silver(I) com-plex of 6-phenyl-2,2':6',2''-terpyridine.
AU - Yuto Nakaie
AU - Tomoya Abe
AU - Yosuke Hosoya
AU - Kosuke Sugawa
AU - Joe Otsuki
PY - 2026
DA - 2026/09/01
JO - IUCrData
DO - 10.1107/s2414314626010436
UR - https://europepmc.org/article/MED/42997380
AB - A dinuclear silver(I) com-plex of 6-phenyl-2,2':6',2''-terpyridine, bis-(μ-6-phenyl-2,2':6',2''-terpyridine)-bis-[(tri-fluoro-methane-sulfonato)-silver(I)], [Ag2(C21H15N3)(CF3SO3)2], was obtained by crystallization with silver tri-fluoro-methane-sulfonate and characterized by single-crystal X-ray diffraction. Two symmetry-related terpyridine ligands bridge two AgI ions. The AgI ion has a highly distorted four-coordinate N3O environment com-prising three pyridyl N atoms and one tri-fluoro-methane-sulfonate O atom. The intra-molecular Ag⋯Ag separation of 2.8501 (8) Å is consistent with an argentophilic inter-action. An intra-molecular phen-yl-pyridyl π-π contact is also present. The structure demonstrates that a single phenyl substituent at the 6-position is com-patible with ligand bridging and the formation of a short Ag⋯Ag contact.
SN - 2414-3146
ER -