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Peer-reviewedCC BY-NCNanoscale Advances

Plasmonic behaviour of poly(2-ethyl-2-oxazoline)-coated gold nanoparticles for sensing and temperature-control applications

Abstract

Gold nanoparticles functionalized with xanthate-poly(2-ethyl-2-oxazoline) (PEtOx-AuNPs) were investigated as thermoresponsive hybrid nanomaterials with tunable optical and thermal properties. The PEtOx-AuNPs exhibited changes in surface plasmon resonance (SPR) and amplified Surface-Enhanced Raman Scattering (SERS) signals during the reversible lower critical solution temperature (LCST) transition of the PEtOx ligand. The effect of the PEtOx coating on the photophysical properties of AuNPs, particularly on heat generation efficiency upon photoexcitation by Z-scan photothermal lens spectroscopy, was investigated. The results demonstrate the potential of PEtOx-AuNPs for applications in temperature-sensitive drug delivery, photothermal therapy, nanoscale heat generation, and photonic devices.

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BibTeX
@article{yeshchenko2026plasmonic,
  title = {{Plasmonic behaviour of poly(2-ethyl-2-oxazoline)-coated gold nanoparticles for sensing and temperature-control applications}},
  author = {Oleg Yeshchenko and Léa Daoud and Pavlo Khort and Oles Fedotov and Julien-Bilal Zinoune and Georges Boudebs and Tony Breton and Catherine Passirani and Patrick Saulnier and Oksana Krupka},
  journal = {Nanoscale Advances},
  year = {2026},
  month = oct,
  doi = {10.1039/d5na00243e},
  url = {https://hal.science/hal-05785565v1},
  note = {CC BY-NC},
}
RIS
TY  - JOUR
TI  - Plasmonic behaviour of poly(2-ethyl-2-oxazoline)-coated gold nanoparticles for sensing and temperature-control applications
AU  - Oleg Yeshchenko
AU  - Léa Daoud
AU  - Pavlo Khort
AU  - Oles Fedotov
AU  - Julien-Bilal Zinoune
AU  - Georges Boudebs
AU  - Tony Breton
AU  - Catherine Passirani
AU  - Patrick Saulnier
AU  - Oksana Krupka
PY  - 2026
DA  - 2026/10/08
JO  - Nanoscale Advances
DO  - 10.1039/d5na00243e
UR  - https://hal.science/hal-05785565v1
AB  - Gold nanoparticles functionalized with xanthate-poly(2-ethyl-2-oxazoline) (PEtOx-AuNPs) were investigated as thermoresponsive hybrid nanomaterials with tunable optical and thermal properties. The PEtOx-AuNPs exhibited changes in surface plasmon resonance (SPR) and amplified Surface-Enhanced Raman Scattering (SERS) signals during the reversible lower critical solution temperature (LCST) transition of the PEtOx ligand. The effect of the PEtOx coating on the photophysical properties of AuNPs, particularly on heat generation efficiency upon photoexcitation by Z-scan photothermal lens spectroscopy, was investigated. The results demonstrate the potential of PEtOx-AuNPs for applications in temperature-sensitive drug delivery, photothermal therapy, nanoscale heat generation, and photonic devices.
SN  - 2516-0230
ER  -