Skip to content
DraconiticResearch
Search Sources API
203,948 studies31 sourcesUpdated 39 min ago
Peer-reviewedCC BYActa crystallographica. Section E, Crystallographic communications

Synthesis and crystal structure of the mixed-valent TeIV/VI compound PbTe₃O₈.

  • Matthias Weil1
  1. 1Institute for Chemical Technologies and Analytics, Division of Applied Solid State Chemistry, TU Wien, Getreidemarkt 9/E164-05-1, A-1060, Vienna, Austria.
Read full textPDFDOICite

Abstract

The crystal structure of the mixed-valent compound PbTe3O8(= PbIITeIV2TeVIO8), lead(II) bis-[oxidotellurate(IV)] tellurate(VI), is isotypic with that of SrTe3O8. It comprises 1∞[Te3O8]2- chains sharing O atoms to form a framework with two types of square channels extending parallel to [001]. The smaller channels (diameter ∼4 Å) are occupied by 12-coordinate PbII atoms in the centre of the channel, whereas the slightly larger channels (diameter ∼4.5 Å) accommodate the stereoactive 5s2 electron lone pair of TeIV.

Related

  1. Synthesis and crystal structure of a one-dimensional Hg(II) coordination polymer with two distinct metal centers and its selective fluorescent sensing of Ni²⁺
    Zohreh Derikvand, Ameneh Jahani Chegeni
    Scientific ReportsPeer-reviewedCC BY-NC-ND 4.0Full textInorganic & organometallic chemistryCrossref
  2. Synthesis and crystal structure of di­bromido­bis­[1-butyl-4-(pyridin-2-yl)-1,2,4-triazol-5-yl­idene]palladium(II)
    Anes Kovacevic, Sean Parkin
    Acta Crystallographica Section E: Crystallographic CommunicationsPeer-reviewedCC BYFull textGeneral chemistryEurope PMC
  3. Synthesis, Crystal Structure, Hirshfeld Surface, Vibrational Thermal Analyses, and NLO Properties of a New Hybrid Material: 2,4-Diamino-6-Phenyl-1,3,5-Triazinium Perchlorate, Supported by DFT Calculations
    Louiza Ouksel, Rima Kiche, Lotfi Boudjema +4
    Molecules (Basel, Switzerland)Peer-reviewedCC BYFull textMaterials & polymersEurope PMCHAL
  4. Synthesis, crystal structure, Hirshfeld surface analysis and halogen-involving interactions in a bromo/chloro-substituted Schiff base 1-(3-bromo-4,5-dimethoxyphenyl)-N-(2,4-dichlorophenyl)methanimine
    Charef Tabti, Hafsa Khaldi, Abdelmadjid Benmohammed +4
    Acta Crystallographica Section C : Structural Chemistry [2014-...]Peer-reviewedPublisher termsFull textInorganic & organometallic chemistryOrganic chemistryHAL
  5. Eco-friendly Synthesis of 3-Methyl-4-arylmethyleneisoxazol-5(4H)-ones. Crystal Structure, Hirshfeld Surface Analysis, and Theoretical Study
    Chaima Boureghda, Hibet Errahmane Meroua Akkache, Mohamed Abdesselem Dems +6
    Organic Preparations and Procedures International : The New Journal for Organic SynthesisPeer-reviewedCC BY-NC 4.0Full textOrganic chemistryHAL

Cite

BibTeXRIS
BibTeX
@article{weil2026synthesis,
  title = {{Synthesis and crystal structure of the mixed-valent TeIV/VI compound PbTe₃O₈.}},
  author = {Matthias Weil},
  journal = {Acta crystallographica. Section E, Crystallographic communications},
  year = {2026},
  month = oct,
  doi = {10.1107/s2056989026010996},
  url = {https://europepmc.org/article/MED/42997426},
  note = {CC BY},
}
RIS
TY  - JOUR
TI  - Synthesis and crystal structure of the mixed-valent TeIV/VI compound PbTe₃O₈.
AU  - Matthias Weil
PY  - 2026
DA  - 2026/10/30
JO  - Acta crystallographica. Section E, Crystallographic communications
DO  - 10.1107/s2056989026010996
UR  - https://europepmc.org/article/MED/42997426
AB  - The crystal structure of the mixed-valent compound PbTe3O8(= PbIITeIV2TeVIO8), lead(II) bis-[oxidotellurate(IV)] tellurate(VI), is isotypic with that of SrTe3O8. It comprises 1∞[Te3O8]2- chains sharing O atoms to form a framework with two types of square channels extending parallel to [001]. The smaller channels (diameter ∼4 Å) are occupied by 12-coordinate PbII atoms in the centre of the channel, whereas the slightly larger channels (diameter ∼4.5 Å) accommodate the stereoactive 5s2 electron lone pair of TeIV.
SN  - 2056-9890
ER  -