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Peer-reviewedCC BY-NC 4.0Chemistry of Metals and Alloys

Crystal structure of URu4Si2, a new Ru-rich phase in the U–Ru–Si ternary system

Abstract

A novel ternary silicide, URu4Si2, has been found in the Ru-rich corner of the U–Ru–Si ternary system. It crystallizes in an orthorhombic unit cell, a = 11.1322(4) Å, b = 4.0823(2) Å, c = 9.0612(5) Å, with space group Pnma and seven occupied 4c atomic positions, corresponding to the YRh4Ge2 structure-type, an ordered variant of the BaHg6 type.

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BibTeX
@article{bekkachi2026crystal,
  title = {{Crystal structure of URu4Si2, a new Ru-rich phase in the U–Ru–Si ternary system}},
  author = {Houda El Bekkachi and Henri Noël and Mathieu Pasturel},
  journal = {Chemistry of Metals and Alloys},
  year = {2026},
  month = oct,
  doi = {10.30970/cma19.0465},
  url = {https://hal.science/hal-05780820v1},
  note = {CC BY-NC 4.0},
}
RIS
TY  - JOUR
TI  - Crystal structure of URu4Si2, a new Ru-rich phase in the U–Ru–Si ternary system
AU  - Houda El Bekkachi
AU  - Henri Noël
AU  - Mathieu Pasturel
PY  - 2026
DA  - 2026/10/06
JO  - Chemistry of Metals and Alloys
DO  - 10.30970/cma19.0465
UR  - https://hal.science/hal-05780820v1
AB  - A novel ternary silicide, URu4Si2, has been found in the Ru-rich corner of the U–Ru–Si ternary system. It crystallizes in an orthorhombic unit cell, a = 11.1322(4) Å, b = 4.0823(2) Å, c = 9.0612(5) Å, with space group Pnma and seven occupied 4c atomic positions, corresponding to the YRh4Ge2 structure-type, an ordered variant of the BaHg6 type.
SN  - 1998-8079
ER  -