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PreprintarXiv licencearXiv

Valley- and Spin-Dependent Electronic and Transport Properties of Two-Dimensional Altermagnetic Titanium-Based Chalcogenide Halides

Abstract

Altermagnets (AMs) combine fully compensated magnetization with momentum-dependent spin splitting, yet intrinsic altermagnetic materials exhibiting exceptional valley characteristics remain scarce. Here, we identify monolayer titanium-based chalcogenide halides, Ti2X2Y (X = F, Cl, Br, I; Y = O, S, Se, Te), as a new family of two-dimensional altermagnetic valley materials. These monolayers exhibit robust d-wave altermagnetic order, semiconducting band gaps, and pronounced spin-polarized valley characteristics. We show that uniaxial strain breaks the valley degeneracy, inducing giant valley polarization together with a tunable piezomagnetic response. An in-plane electric field generates noncollinear spin currents, while spin--orbit coupling gives rise to the anomalous Hall effect, valley-selective linear dichroism, and the magneto-optical Kerr effect. These findings establish Ti2X2Y monolayers as a versatile platform for exploring spin- and valley-dependent electronic, optical, and transport phenomena in two-dimensional altermagnets.

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BibTeX
@misc{ning2026valley,
  title = {{Valley- and Spin-Dependent Electronic and Transport Properties of Two-Dimensional Altermagnetic Titanium-Based Chalcogenide Halides}},
  author = {Ruo-Yu Ning and Zhi-Hua Yan and Jin-Yang Li and Yong-Kun Wang and Si Li},
  howpublished = {arXiv},
  year = {2026},
  month = sep,
  doi = {10.48550/arxiv.2608.19734},
  eprint = {2608.19734},
  archivePrefix = {arXiv},
  url = {https://arxiv.org/abs/2608.19734},
}
RIS
TY  - UNPB
TI  - Valley- and Spin-Dependent Electronic and Transport Properties of Two-Dimensional Altermagnetic Titanium-Based Chalcogenide Halides
AU  - Ruo-Yu Ning
AU  - Zhi-Hua Yan
AU  - Jin-Yang Li
AU  - Yong-Kun Wang
AU  - Si Li
PY  - 2026
DA  - 2026/09/14
PB  - arXiv
DO  - 10.48550/arxiv.2608.19734
UR  - https://arxiv.org/abs/2608.19734
AB  - Altermagnets (AMs) combine fully compensated magnetization with momentum-dependent spin splitting, yet intrinsic altermagnetic materials exhibiting exceptional valley characteristics remain scarce. Here, we identify monolayer titanium-based chalcogenide halides, Ti_2X_2Y (X = F, Cl, Br, I; Y = O, S, Se, Te), as a new family of two-dimensional altermagnetic valley materials. These monolayers exhibit robust d-wave altermagnetic order, semiconducting band gaps, and pronounced spin-polarized valley characteristics. We show that uniaxial strain breaks the valley degeneracy, inducing giant valley polarization together with a tunable piezomagnetic response. An in-plane electric field generates noncollinear spin currents, while spin--orbit coupling gives rise to the anomalous Hall effect, valley-selective linear dichroism, and the magneto-optical Kerr effect. These findings establish Ti_2X_2Y monolayers as a versatile platform for exploring spin- and valley-dependent electronic, optical, and transport phenomena in two-dimensional altermagnets.
ER  -