Powder-in-tube confinement as a design principle for fatigue-resistant caloric materials
Abstract
Caloric solid-state refrigeration offers an energy-efficient alternative to vapor-compression cooling, but many of the most promising materials, including the magneto- and elastocaloric Heusler alloys, are intrinsically brittle and fail under the cyclic loading required in operation. Here, we introduce mechanical confinement via powder-in-tube (PIT) processing as a general strategy to overcome this limitation. By embedding a granular Heusler alloy core of 87 % packing density within a ductile steel sheath (2.8 mm outer diameter, 0.3 mm wall thickness), the composite confines the brittle powder and enables effective load transfer between particles. While the core remains inherently brittle, the surrounding sheath prevents catastrophic fragmentation and turns brittleness from a disqualifying property into a manageable one. We demonstrate that this approach enhances mechanical durability by several orders of magnitude, with the composites sustaining 100,000 load cycles at 250 MPa without structural failure and tolerating overload stresses up to 700 MPa. Confinement also alters the transformation itself, and to resolve this behavior in these mechanically complex systems, we developed a simultaneous in-situ measurement technique combining strain and AC magnetic susceptibility under load. It reveals that the internal stress field in the core is strongly heterogeneous. As a consequence, the macroscopic strain decouples from the transforming phase fraction, and the martensitic transition cannot be tracked by mechanical data alone. Mechanical confinement thus emerges as a design principle for fatigue-resistant caloric materials, and the combined in-situ method as a characterization tool for composite, porous, and other mechanically heterogeneous caloric systems.
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BibTeX
@misc{niehoff2026powderintube,
title = {{Powder-in-tube confinement as a design principle for fatigue-resistant caloric materials}},
author = {T. Niehoff and L. Beyer and J. Puy and F. Scheibel and J. Freudenberger and O. Gutfleisch and J. Wosnitza and T. Gottschall},
howpublished = {arXiv},
year = {2026},
month = oct,
doi = {10.48550/arxiv.2610.08172},
eprint = {2610.08172},
archivePrefix = {arXiv},
url = {https://arxiv.org/abs/2610.08172},
note = {CC BY-SA 4.0},
}
RIS
TY - UNPB
TI - Powder-in-tube confinement as a design principle for fatigue-resistant caloric materials
AU - T. Niehoff
AU - L. Beyer
AU - J. Puy
AU - F. Scheibel
AU - J. Freudenberger
AU - O. Gutfleisch
AU - J. Wosnitza
AU - T. Gottschall
PY - 2026
DA - 2026/10/06
PB - arXiv
DO - 10.48550/arxiv.2610.08172
UR - https://arxiv.org/abs/2610.08172
AB - Caloric solid-state refrigeration offers an energy-efficient alternative to vapor-compression cooling, but many of the most promising materials, including the magneto- and elastocaloric Heusler alloys, are intrinsically brittle and fail under the cyclic loading required in operation. Here, we introduce mechanical confinement via powder-in-tube (PIT) processing as a general strategy to overcome this limitation. By embedding a granular Heusler alloy core of 87 % packing density within a ductile steel sheath (2.8 mm outer diameter, 0.3 mm wall thickness), the composite confines the brittle powder and enables effective load transfer between particles. While the core remains inherently brittle, the surrounding sheath prevents catastrophic fragmentation and turns brittleness from a disqualifying property into a manageable one. We demonstrate that this approach enhances mechanical durability by several orders of magnitude, with the composites sustaining 100,000 load cycles at 250 MPa without structural failure and tolerating overload stresses up to 700 MPa. Confinement also alters the transformation itself, and to resolve this behavior in these mechanically complex systems, we developed a simultaneous in-situ measurement technique combining strain and AC magnetic susceptibility under load. It reveals that the internal stress field in the core is strongly heterogeneous. As a consequence, the macroscopic strain decouples from the transforming phase fraction, and the martensitic transition cannot be tracked by mechanical data alone. Mechanical confinement thus emerges as a design principle for fatigue-resistant caloric materials, and the combined in-situ method as a characterization tool for composite, porous, and other mechanically heterogeneous caloric systems.
ER -