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Peer-reviewedCC BY 4.0Batteries

Thermal Runaway Characteristics of Batteries with Manganese-Based Composite Cathode Materials Triggered by Electromagnetic Induction Heating and Lateral Heating

  1. 1State Key Laboratory of Intelligent Green Vehicle and Mobility (SKLIGVM), School of Vehicle and Mobility, Tsinghua University, Beijing 100084, China
  2. 2School of Mechanical Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China

Abstract

Trigger selection underpins thermal runaway (TR) and thermal propagation (TP) testing of lithium-ion batteries, yet its influence on the TR response is rarely quantified, and data for a cell with manganese-based composite cathode (MCC) material are scarce. Here, a fully charged 130 Ah prismatic cell using MCC was driven into TR by high-frequency electromagnetic induction heating and by lateral plate heating in identical fixtures, and each response was resolved into four stages. A 12-s induction pulse initiated TR from a local nucleus: flame ejection followed venting by 9 s, the trigger-point temperature peaked at 682.6 °C, and the voltage collapsed in two stages with a ~3.0-V, ~14-s plateau, the signature of an expanding local short circuit. Lateral heating required 273 s of whole-cell preheating and produced a faster, hotter event: a jet flame ~20 s after venting, whole-cell involvement within 10.4 s, a 775.4 °C peak, and a single-stage ~20-s collapse. Induction heating thus provides rapid, position-selectable initiation with minimal additional energy input, which is well suited to propagation testing, whereas standard-compliant lateral heating represents external-fire abuse; these results provide the first cell-level reference data for MCC thermal runaway, quantify how the triggering method alone alters the TR response, and identify the voltage-collapse morphology as a diagnostic of the initiation mode.

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BibTeX
@article{jin2026thermal,
  title = {{Thermal Runaway Characteristics of Batteries with Manganese-Based Composite Cathode Materials Triggered by Electromagnetic Induction Heating and Lateral Heating}},
  author = {Changyong Jin and Shiding Zhou and Jing Feng and Hongxu Li and Chengshan Xu},
  journal = {Batteries},
  year = {2026},
  month = oct,
  doi = {10.3390/batteries12100418},
  url = {https://www.mdpi.com/2313-0105/12/10/418},
  note = {CC BY 4.0},
}
RIS
TY  - JOUR
TI  - Thermal Runaway Characteristics of Batteries with Manganese-Based Composite Cathode Materials Triggered by Electromagnetic Induction Heating and Lateral Heating
AU  - Changyong Jin
AU  - Shiding Zhou
AU  - Jing Feng
AU  - Hongxu Li
AU  - Chengshan Xu
PY  - 2026
DA  - 2026/10/12
JO  - Batteries
DO  - 10.3390/batteries12100418
UR  - https://www.mdpi.com/2313-0105/12/10/418
AB  - Trigger selection underpins thermal runaway (TR) and thermal propagation (TP) testing of lithium-ion batteries, yet its influence on the TR response is rarely quantified, and data for a cell with manganese-based composite cathode (MCC) material are scarce. Here, a fully charged 130 Ah prismatic cell using MCC was driven into TR by high-frequency electromagnetic induction heating and by lateral plate heating in identical fixtures, and each response was resolved into four stages. A 12-s induction pulse initiated TR from a local nucleus: flame ejection followed venting by 9 s, the trigger-point temperature peaked at 682.6 °C, and the voltage collapsed in two stages with a ~3.0-V, ~14-s plateau, the signature of an expanding local short circuit. Lateral heating required 273 s of whole-cell preheating and produced a faster, hotter event: a jet flame ~20 s after venting, whole-cell involvement within 10.4 s, a 775.4 °C peak, and a single-stage ~20-s collapse. Induction heating thus provides rapid, position-selectable initiation with minimal additional energy input, which is well suited to propagation testing, whereas standard-compliant lateral heating represents external-fire abuse; these results provide the first cell-level reference data for MCC thermal runaway, quantify how the triggering method alone alters the TR response, and identify the voltage-collapse morphology as a diagnostic of the initiation mode.
SN  - 2313-0105
ER  -