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Peer-reviewedCC BY 4.0Chemistry (Weinheim an Der Bergstrasse, Germany)

Syntheses and Properties of Pentafluoroethylplumbanes in the Oxidation States +II, +III, and +IV

  • Michael Grasse1
  • Lukas Hartmann1
  • Beate Neumann1
  • Hans‐Georg Stammler1
  • Berthold Hoge1
  1. 1Fakultät für Chemie Centrum für Molekulare Materialien Universität Bielefeld Bielefeld Germany
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Abstract

Mono‐, bis‐, and tris(pentafluoroethyl)plumbanes of the type Pb(C2F5) n Ar4‐

n (Ar = Ph, Tol, Ani; n = 1–3) are easily accessible by treatment of the corresponding arylchloroplumbanes with LiC2F5. The subsequent treatment with HCl furnishes chloro(pentafluoroethyl)plumbanes. The synthesis of the tris(pentafluoroethyl)plumbate(II) anion is facilitated by treatment of Pb(C2F5)3Cl with PPh3. In addition, formation of Pb(C2F5)4 is achieved starting from Pb(OAc)4 and is fully characterized by multinuclear NMR spectroscopy and by single crystal x‐ray diffraction of the 1,10‐phenanthroline adduct.

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Cite

BibTeXRIS
BibTeX
@article{grasse2026syntheses,
  title = {{Syntheses and Properties of Pentafluoroethylplumbanes in the Oxidation States +II, +III, and +IV}},
  author = {Michael Grasse and Lukas Hartmann and Beate Neumann and Hans‐Georg Stammler and Berthold Hoge},
  journal = {Chemistry (Weinheim an Der Bergstrasse, Germany)},
  year = {2026},
  month = jul,
  doi = {10.1002/chem.71402},
  url = {https://doi.org/10.1002/chem.71402},
  note = {CC BY 4.0},
}
RIS
TY  - JOUR
TI  - Syntheses and Properties of Pentafluoroethylplumbanes in the Oxidation States +II, +III, and +IV
AU  - Michael Grasse
AU  - Lukas Hartmann
AU  - Beate Neumann
AU  - Hans‐Georg Stammler
AU  - Berthold Hoge
PY  - 2026
DA  - 2026/07/18
JO  - Chemistry (Weinheim an Der Bergstrasse, Germany)
DO  - 10.1002/chem.71402
UR  - https://doi.org/10.1002/chem.71402
AB  - Mono‐, bis‐, and tris(pentafluoroethyl)plumbanes of the type Pb(C2F5) n Ar4‐  n (Ar = Ph, Tol, Ani; n = 1–3) are easily accessible by treatment of the corresponding arylchloroplumbanes with LiC2F5. The subsequent treatment with HCl furnishes chloro(pentafluoroethyl)plumbanes. The synthesis of the tris(pentafluoroethyl)plumbate(II) anion is facilitated by treatment of Pb(C2F5)3Cl with PPh3. In addition, formation of Pb(C2F5)4 is achieved starting from Pb(OAc)4 and is fully characterized by multinuclear NMR spectroscopy and by single crystal x‐ray diffraction of the 1,10‐phenanthroline adduct.
SN  - 0947-6539
SN  - 1521-3765
ER  -