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Peer-reviewedCC BYRSC advances

A hybrid ceramifiable hydrophobic coating with integrated fire-resistance and weatherability.

  1. 1School of Aeronautics, Shanghai Dianji University Shanghai 201306 China [email protected].
  2. 2Zhejiang Marine Development Research Institute Zhoushan Zhejiang 316021 China [email protected].

Abstract

Steel structures in coastal oil and gas facilities are particularly susceptible to corrosion and fire hazards, posing significant challenges to structural integrity and fire safety. Anti-corrosion coatings provide excellent corrosion resistance for the steel, while, in the case of the 1200 °C flame conditions, inorganic passive fire protection coating provides superior to fire performance than the organic coating. Here, a hybrid ceramifiable hydrophobic coating was developed by incorporating a high loading of two-dimensional flake fillers into a silicone resin matrix to enhance fire resistance of organic anticorrosion-coated structural steel. The results indicate that the developed coating exhibits excellent fire-resistance and weatherability. Under a 1200 °C flame, the fire-resistant coating protected the steel plate for at least 30 minutes without peeling, while limiting the backside temperature to approximately 535 °C. Moreover, the weatherability of the coating was assessed via accelerated environmental aging, including corrosive and damp-heat environments. This excellent stability is attributed to the dense packing of the flake fillers and the inherent hydrophobicity of the silicone resin. These findings not only provide condensed-phase fire protection but also serve as a candidate for the potential future applications in diverse extreme service conditions, such as lithium-ion battery enclosures.

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BibTeX
@article{zhang2026hybrid,
  title = {{A hybrid ceramifiable hydrophobic coating with integrated fire-resistance and weatherability.}},
  author = {Junhui Zhang and Guanyuan Zheng and Haichun Zhang and Xiru Zhang and Baoku Sun and Ading Lu and Huisheng Fan and Dandan Jin and Lei Li},
  journal = {RSC advances},
  year = {2026},
  month = oct,
  doi = {10.1039/d6ra08072c},
  url = {https://europepmc.org/article/MED/42840495},
  note = {CC BY},
}
RIS
TY  - JOUR
TI  - A hybrid ceramifiable hydrophobic coating with integrated fire-resistance and weatherability.
AU  - Junhui Zhang
AU  - Guanyuan Zheng
AU  - Haichun Zhang
AU  - Xiru Zhang
AU  - Baoku Sun
AU  - Ading Lu
AU  - Huisheng Fan
AU  - Dandan Jin
AU  - Lei Li
PY  - 2026
DA  - 2026/10/06
JO  - RSC advances
DO  - 10.1039/d6ra08072c
UR  - https://europepmc.org/article/MED/42840495
AB  - Steel structures in coastal oil and gas facilities are particularly susceptible to corrosion and fire hazards, posing significant challenges to structural integrity and fire safety. Anti-corrosion coatings provide excellent corrosion resistance for the steel, while, in the case of the 1200 °C flame conditions, inorganic passive fire protection coating provides superior to fire performance than the organic coating. Here, a hybrid ceramifiable hydrophobic coating was developed by incorporating a high loading of two-dimensional flake fillers into a silicone resin matrix to enhance fire resistance of organic anticorrosion-coated structural steel. The results indicate that the developed coating exhibits excellent fire-resistance and weatherability. Under a 1200 °C flame, the fire-resistant coating protected the steel plate for at least 30 minutes without peeling, while limiting the backside temperature to approximately 535 °C. Moreover, the weatherability of the coating was assessed via accelerated environmental aging, including corrosive and damp-heat environments. This excellent stability is attributed to the dense packing of the flake fillers and the inherent hydrophobicity of the silicone resin. These findings not only provide condensed-phase fire protection but also serve as a candidate for the potential future applications in diverse extreme service conditions, such as lithium-ion battery enclosures.
SN  - 2046-2069
ER  -