Chiral Temporal Structures in Molecular Rotational Dynamics
Abstract
We introduce chiral rotational wavepackets: coherent superpositions of a few low-lying rotational states of a molecule for which the expectation value of a molecular axis traces a three-dimensional chiral trajectory in the laboratory frame. The handedness is a dynamical property of the quantum state rather than of the equilibrium structure, and we show that it can be imprinted on linear rotors as well as on spherical and symmetric tops. We derive the action of space inversion, time reversal, and their product on such wavepackets in the Wigner DJMK basis, and define the rotational enantiomers of a given wavepacket. To quantify their handedness we introduce two derivative-based pseudoscalar measures: a geometrical measure built from the curvature and torsion of the trajectory, which is even under time reversal, and a dynamical measure, which is odd under time reversal. The latter is shown to be proportional to the geodesic curvature of the trajectory projected onto the unit sphere, which links it, via the Gauss--Bonnet theorem, to the solid angle enclosed by the projected trajectory and to the parallel-transport holonomy of a molecule-fixed vector. Finally we show that a nonzero geometrical measure is a sufficient condition for the wavepacket to exhibit true chirality through its orientation trajectory in the sense of Barron.
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BibTeX
@misc{lohr2026chiral,
title = {{Chiral Temporal Structures in Molecular Rotational Dynamics}},
author = {A. G. Löhr and O. Smirnova and M. Mirahmadi},
howpublished = {arXiv},
year = {2026},
month = oct,
doi = {10.48550/arxiv.2609.37896},
eprint = {2609.37896},
archivePrefix = {arXiv},
url = {https://arxiv.org/abs/2609.37896},
note = {CC BY 4.0},
}
RIS
TY - UNPB
TI - Chiral Temporal Structures in Molecular Rotational Dynamics
AU - A. G. Löhr
AU - O. Smirnova
AU - M. Mirahmadi
PY - 2026
DA - 2026/10/13
PB - arXiv
DO - 10.48550/arxiv.2609.37896
UR - https://arxiv.org/abs/2609.37896
AB - We introduce chiral rotational wavepackets: coherent superpositions of a few low-lying rotational states of a molecule for which the expectation value of a molecular axis traces a three-dimensional chiral trajectory in the laboratory frame. The handedness is a dynamical property of the quantum state rather than of the equilibrium structure, and we show that it can be imprinted on linear rotors as well as on spherical and symmetric tops. We derive the action of space inversion, time reversal, and their product on such wavepackets in the Wigner D^J_MK basis, and define the rotational enantiomers of a given wavepacket. To quantify their handedness we introduce two derivative-based pseudoscalar measures: a geometrical measure built from the curvature and torsion of the trajectory, which is even under time reversal, and a dynamical measure, which is odd under time reversal. The latter is shown to be proportional to the geodesic curvature of the trajectory projected onto the unit sphere, which links it, via the Gauss--Bonnet theorem, to the solid angle enclosed by the projected trajectory and to the parallel-transport holonomy of a molecule-fixed vector. Finally we show that a nonzero geometrical measure is a sufficient condition for the wavepacket to exhibit true chirality through its orientation trajectory in the sense of Barron.
ER -