Skip to content
DraconiticResearch
Search Sources API
203,234 studies31 sourcesUpdated 51 min ago
PreprintCC BYChemRxiv

Broadband Visible Emission from a Rigid Ground State in an Ionic Zn-MOF Single Crystal

  • Laura Nathalia Diaz-Rozo1
  • Arthur Mantel2
  • Hidetsugu Shiozawa1,2
  1. 1Faculty of Physics, University of Vienna, Boltzmanngasse 5, Vienna, Vienna, Austria, 1090
  2. 2Heyrovsky Institute of the CAS, Dolejskova 2155/3, Prague, Prague, Czechia, 182 00
Open at sourcePDFDOICite

Abstract

Single crystals of the ionic MOF {[Zn 2 (BDC) 2 (OAc)] -} 2 [Zn(DMSO) 6 ] 2+ have been grown and their photoluminescence recorded as excitation-emission maps.Solvated crystals in the mother liquor, dimethyl sulfoxide, and 1,2-dichloroethane exhibit broadband visible emission centred at approximately 440 nm under a narrow excitation band near 300 nm.The sharp excitation indicates excitation of the linker in a well-defined ground-state geometry rather than of a heterogeneous defect ensemble.The featureless visible envelope is attributed to subsequent structural relaxations on the excited-state potential-energy surface.The same motif is observed for optically clear and cloudy crystals, supporting the assignment of the emission as intrinsic to the framework rather than defect-centred.

Related

  1. Broadband near-infrared emission in Tm3+-doped high-entropy (Lu,Y,Sc,Gd)2O3 crystal fibers grown by LHPG
    Liuyin Sun, Jian Liu, Xinyu Guo +5
    Journal of LuminescencePeer-reviewedCC BY-NC-ND 4.0Full textMaterials & polymersHAL
  2. Hydrothermally synthesised Gd2Te4O11 nanorods for broadband visible light photodetection and NLO applications
    Manoranjan Sahoo, Prabhukrupa Chinmay Kumar, Ramakanta Naik
    Nanoscale AdvancesPeer-reviewedCC BY-NC 3.0Full textMaterials & polymersPMC
  3. Monolayer MoS₂ on Paper with a Copper Electrode: An Integrated CVD-Grown Broadband UV-Visible Photodetector.
    Amal Alzahrani, Maha Alaqeel, Mohamed Nejib Hedhili +6
    MicromachinesPeer-reviewedCC BYFull textMaterials & polymersEurope PMC
  4. Reconciling visible emission intensity and ON/OFF commutation ratio in photochromic lanthanide complexes of europium(III) and samarium(III).
    Yoann Fréroux, Salauat R. Kiraev, Olivier Maury +2
    ChemRxivPreprintLicence not statedGeneral chemistryChemRxiv
  5. Demonstration of Broadband Non-Resonant Time-Crystal Amplification in Microwaves
    Thomas R. Jones, Ludmila J. Prokopeva, Alexander V. Kildishev +2
    arXiv (Cornell University)PreprintCC BYFull text6 citedMaterials & polymersOpenAlex

Cite

BibTeXRIS
BibTeX
@misc{diazrozo2026broadband,
  title = {{Broadband Visible Emission from a Rigid Ground State in an Ionic Zn-MOF Single Crystal}},
  author = {Laura Nathalia Diaz-Rozo and Arthur Mantel and Hidetsugu Shiozawa},
  howpublished = {ChemRxiv},
  year = {2026},
  month = sep,
  doi = {10.26434/chemrxiv.15008613/v1},
  url = {https://chemrxiv.org/doi/full/10.26434/chemrxiv.15008613/v1},
  note = {CC BY},
}
RIS
TY  - UNPB
TI  - Broadband Visible Emission from a Rigid Ground State in an Ionic Zn-MOF Single Crystal
AU  - Laura Nathalia Diaz-Rozo
AU  - Arthur Mantel
AU  - Hidetsugu Shiozawa
PY  - 2026
DA  - 2026/09/10
PB  - ChemRxiv
DO  - 10.26434/chemrxiv.15008613/v1
UR  - https://chemrxiv.org/doi/full/10.26434/chemrxiv.15008613/v1
AB  - Single crystals of the ionic MOF {[Zn 2 (BDC) 2 (OAc)] -} 2 [Zn(DMSO) 6 ] 2+ have been grown and their photoluminescence recorded as excitation-emission maps.Solvated crystals in the mother liquor, dimethyl sulfoxide, and 1,2-dichloroethane exhibit broadband visible emission centred at approximately 440 nm under a narrow excitation band near 300 nm.The sharp excitation indicates excitation of the linker in a well-defined ground-state geometry rather than of a heterogeneous defect ensemble.The featureless visible envelope is attributed to subsequent structural relaxations on the excited-state potential-energy surface.The same motif is observed for optically clear and cloudy crystals, supporting the assignment of the emission as intrinsic to the framework rather than defect-centred.
ER  -