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PreprintCC BY 4.0arXiv

Long Time Behaviour of the Two-Component Becker-Döring System

Abstract

The classical Becker-Döring equations describe the formation of clusters by aggregation and fragmentation of monomers. If the total amount of mass is supercritical, larger and larger clusters are formed, leading to an asymptotic loss of mass in the long time limit. The two-component Becker-Döring system arises when clusters are built from two types of monomers. Here, we study the natural extension of the one-component system, where no energy or entropy is leaving or entering the system - the so called detailed balance assumption. We rigorously prove that all initial conditions admit a solution minimising the relative entropy as time approaches infinity. This shows, that the long time limit in the weak* topology is selected through the initial Type I and Type II masses. Furthermore, the proportion of lost Type I mass is determined by the limit point via the mixing ratio of Type I and Type II monomers that maximises the binding energy. The main difficulty of the two-component system is that no relative entropy is weak* continuous, which is crucial for the classical argument [2]. Instead, our proof is based on a discrete two-dimensional logarithmic Sobolev inequality, that bounds the entropy dissipation on the correct timescale. Our approach also improves current assumptions to determine the long time behaviour for the one-component system.

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BibTeX
@misc{scholten2026long,
  title = {{Long Time Behaviour of the Two-Component Becker-Döring System}},
  author = {Jens Scholten},
  howpublished = {arXiv},
  year = {2026},
  month = sep,
  doi = {10.48550/arxiv.2609.29891},
  eprint = {2609.29891},
  archivePrefix = {arXiv},
  url = {https://arxiv.org/abs/2609.29891},
  note = {CC BY 4.0},
}
RIS
TY  - UNPB
TI  - Long Time Behaviour of the Two-Component Becker-Döring System
AU  - Jens Scholten
PY  - 2026
DA  - 2026/09/25
PB  - arXiv
DO  - 10.48550/arxiv.2609.29891
UR  - https://arxiv.org/abs/2609.29891
AB  - The classical Becker-Döring equations describe the formation of clusters by aggregation and fragmentation of monomers. If the total amount of mass is supercritical, larger and larger clusters are formed, leading to an asymptotic loss of mass in the long time limit. The two-component Becker-Döring system arises when clusters are built from two types of monomers. Here, we study the natural extension of the one-component system, where no energy or entropy is leaving or entering the system - the so called detailed balance assumption. We rigorously prove that all initial conditions admit a solution minimising the relative entropy as time approaches infinity. This shows, that the long time limit in the weak* topology is selected through the initial Type I and Type II masses. Furthermore, the proportion of lost Type I mass is determined by the limit point via the mixing ratio of Type I and Type II monomers that maximises the binding energy. The main difficulty of the two-component system is that no relative entropy is weak* continuous, which is crucial for the classical argument [2]. Instead, our proof is based on a discrete two-dimensional logarithmic Sobolev inequality, that bounds the entropy dissipation on the correct timescale. Our approach also improves current assumptions to determine the long time behaviour for the one-component system.
ER  -