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Peer-reviewedCC BY-NC 4.0Chemical Communications

H2 Activation by a Borane-Modified [FeFe]-Hydrogenase Model forming an Intramolecular Frustrated Lewis Pair

  • Victor Monnot
  • Jean-Baptiste Breton
  • Federica Arrigoni
  • Kevin Maineri
  • Giuseppe Zampella
  • Philippe Schollhammer
  • Lucile Chatelain
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Abstract

The H2 molecule, a green energy vector, is cleaved without noble metals by an {Fe2S2} complex functionalized via hydroboration of allyldiphenylphosphine. The pair formed by the boron-based Lewis acid and the {FeFe} center functions as a Frustrated Lewis Pair. Computational studies allow the proposed mechanism of intramolecular cooperative H2 splitting to be rationalized.

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Cite

BibTeXRIS
BibTeX
@article{monnot2026activation,
  title = {{H2 Activation by a Borane-Modified [FeFe]-Hydrogenase Model forming an Intramolecular Frustrated Lewis Pair}},
  author = {Victor Monnot and Jean-Baptiste Breton and Federica Arrigoni and Kevin Maineri and Giuseppe Zampella and Philippe Schollhammer and Lucile Chatelain},
  journal = {Chemical Communications},
  year = {2026},
  month = oct,
  doi = {10.1039/d6cc05801a},
  url = {https://hal.science/hal-05795020v1},
  note = {CC BY-NC 4.0},
}
RIS
TY  - JOUR
TI  - H2 Activation by a Borane-Modified [FeFe]-Hydrogenase Model forming an Intramolecular Frustrated Lewis Pair
AU  - Victor Monnot
AU  - Jean-Baptiste Breton
AU  - Federica Arrigoni
AU  - Kevin Maineri
AU  - Giuseppe Zampella
AU  - Philippe Schollhammer
AU  - Lucile Chatelain
PY  - 2026
DA  - 2026/10/05
JO  - Chemical Communications
DO  - 10.1039/d6cc05801a
UR  - https://hal.science/hal-05795020v1
AB  - The H2 molecule, a green energy vector, is cleaved without noble metals by an {Fe2S2} complex functionalized via hydroboration of allyldiphenylphosphine. The pair formed by the boron-based Lewis acid and the {FeFe} center functions as a Frustrated Lewis Pair. Computational studies allow the proposed mechanism of intramolecular cooperative H2 splitting to be rationalized.
SN  - 1359-7345
SN  - 1364-548X
ER  -