Ni0.85Se Nanosheet Arrays on Nickel Foam as a Robust Non-Noble Metal Electrocatalyst for Energy-Efficient Urea Oxidation
- 1School of Chemical Engineering, Yeungnam University, Gyeongsan 712-749, Republic of Korea
- 2Department of Chemistry Education, Chonnam National University, Gwangju 500-757, Republic of Korea
Abstract
We report the facile synthesis of Ni0.85Se nanosheet arrays directly grown on nickel foam (NF) via a two-step hydrothermal strategy using Ni(OH)2 as a precursor. The two-dimensional architecture offers abundant electroactive sites and efficient charge transport pathways, resulting in remarkable electrocatalytic activity toward the urea oxidation reaction (UOR). The optimized Ni0.85Se/NF electrode delivers a current density of 10 mA cm−2 at a potential of 1.352 V vs. RHE and exhibits a small Tafel slope of 42.3 mV dec−1. Furthermore, it demonstrates excellent durability, maintaining stable operation for over 120 h in alkaline urea-containing electrolyte. These findings highlight Ni0.85Se nanosheets as a cost-effective and durable non-noble-metal electrocatalyst with significant potential for urea oxidation application.
Related
- Intramolecular oxygen coupling mediates water oxidation on an oxide electrocatalyst
- Enhancing the performance of nickel-cobalt selenide electrocatalyst on hydrochar support for oxygen evolution reaction
- General Preparation of Nickel-Based Compound/Carbon Nanotube Catalysts for the Urea Oxidation Reaction
- Mechanistic Understanding of Nickel Catalyzed Urea Oxidation Reaction to Cyanate and Nitrite
- Exploring nickel-based electrocatalysts for overall alkaline water electrolysis and the hydrogen evolution reaction coupled with the glucose oxidation reaction
BibTeX
@article{rajesh2026ni085se,
title = {{Ni0.85Se Nanosheet Arrays on Nickel Foam as a Robust Non-Noble Metal Electrocatalyst for Energy-Efficient Urea Oxidation}},
author = {John Anthuvan Rajesh and Shrine Maria Nithya Jeghan and Soon-Hyung Kang and Kwang-Soon Ahn},
journal = {Nanomaterials},
year = {2026},
month = oct,
doi = {10.3390/nano16211357},
url = {https://www.mdpi.com/2079-4991/16/21/1357},
note = {CC BY 4.0},
}
RIS
TY - JOUR
TI - Ni0.85Se Nanosheet Arrays on Nickel Foam as a Robust Non-Noble Metal Electrocatalyst for Energy-Efficient Urea Oxidation
AU - John Anthuvan Rajesh
AU - Shrine Maria Nithya Jeghan
AU - Soon-Hyung Kang
AU - Kwang-Soon Ahn
PY - 2026
DA - 2026/10/25
JO - Nanomaterials
DO - 10.3390/nano16211357
UR - https://www.mdpi.com/2079-4991/16/21/1357
AB - We report the facile synthesis of Ni0.85Se nanosheet arrays directly grown on nickel foam (NF) via a two-step hydrothermal strategy using Ni(OH)2 as a precursor. The two-dimensional architecture offers abundant electroactive sites and efficient charge transport pathways, resulting in remarkable electrocatalytic activity toward the urea oxidation reaction (UOR). The optimized Ni0.85Se/NF electrode delivers a current density of 10 mA cm−2 at a potential of 1.352 V vs. RHE and exhibits a small Tafel slope of 42.3 mV dec−1. Furthermore, it demonstrates excellent durability, maintaining stable operation for over 120 h in alkaline urea-containing electrolyte. These findings highlight Ni0.85Se nanosheets as a cost-effective and durable non-noble-metal electrocatalyst with significant potential for urea oxidation application.
SN - 2079-4991
ER -