From Transition-State Geometry to Gap Times: What Lagrangian Betweenness Measures in Chemical Reaction Dynamics
Abstract
A chemical transition state is a phase-space bottleneck: trajectories approach along stable directions and leave along unstable directions. Lagrangian betweenness (LB), introduced in finite-time transport theory for fluid flows, combines backward and forward deformation in a way suggestive of this gather-and-disperse geometry. We ask what LB measures when the transition-state geometry is known. For a linear rank-one saddle, LB is spatially constant even though the stable and unstable manifolds are present. Relative nonlinear corrections remain small on shrinking initial neighborhoods, including observation times on the logarithmic local escape scale. At fixed spatial resolution, however, increasing observation time can concentrate the spatial variation of LB near a stable or unstable manifold. A separable quartic Hamiltonian makes these two limits explicit. A nonseparable Hamiltonian shows local flattening near a hyperbolic periodic orbit. We then use HCN/CNH isomerization, where dividing surfaces and gap times are established by phase-space transition-state theory. Before any exit, larger LB generally accompanies longer eventual gap times. The incoming reactive action provides a dynamical interpretation: initial conditions closer to the normally hyperbolic invariant manifold have longer local passages and greater accumulated stretching during passage. Among trajectories still inside at 0.5 ps that exit before 5 ps, early LB does not usefully rank exit times. LB therefore characterizes transition-state-organized transport in this example; a large value is neither an intrinsic manifold marker nor a general measure of molecular residence time.
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BibTeX
@misc{wiggins2026from,
title = {{From Transition-State Geometry to Gap Times: What Lagrangian Betweenness Measures in Chemical Reaction Dynamics}},
author = {Stephen Wiggins},
howpublished = {arXiv},
year = {2026},
month = sep,
doi = {10.48550/arxiv.2609.14378},
eprint = {2609.14378},
archivePrefix = {arXiv},
url = {https://arxiv.org/abs/2609.14378},
note = {CC BY 4.0},
}
RIS
TY - UNPB
TI - From Transition-State Geometry to Gap Times: What Lagrangian Betweenness Measures in Chemical Reaction Dynamics
AU - Stephen Wiggins
PY - 2026
DA - 2026/09/22
PB - arXiv
DO - 10.48550/arxiv.2609.14378
UR - https://arxiv.org/abs/2609.14378
AB - A chemical transition state is a phase-space bottleneck: trajectories approach along stable directions and leave along unstable directions. Lagrangian betweenness (LB), introduced in finite-time transport theory for fluid flows, combines backward and forward deformation in a way suggestive of this gather-and-disperse geometry. We ask what LB measures when the transition-state geometry is known. For a linear rank-one saddle, LB is spatially constant even though the stable and unstable manifolds are present. Relative nonlinear corrections remain small on shrinking initial neighborhoods, including observation times on the logarithmic local escape scale. At fixed spatial resolution, however, increasing observation time can concentrate the spatial variation of LB near a stable or unstable manifold. A separable quartic Hamiltonian makes these two limits explicit. A nonseparable Hamiltonian shows local flattening near a hyperbolic periodic orbit. We then use HCN/CNH isomerization, where dividing surfaces and gap times are established by phase-space transition-state theory. Before any exit, larger LB generally accompanies longer eventual gap times. The incoming reactive action provides a dynamical interpretation: initial conditions closer to the normally hyperbolic invariant manifold have longer local passages and greater accumulated stretching during passage. Among trajectories still inside at 0.5 ps that exit before 5 ps, early LB does not usefully rank exit times. LB therefore characterizes transition-state-organized transport in this example; a large value is neither an intrinsic manifold marker nor a general measure of molecular residence time.
ER -