Universal link between structural relaxation and self-diffusion in simple supercooled liquids
Abstract
Despite a vigorous effort, a comprehensive and satisfactory understanding of the dynamics underlying the glass transition in finite-dimensional systems has not yet emerged. One key hallmark of supercooled liquids approaching the glass transition is the breakdown of the classical Stokes-Einstein (SE) relation, manifested as the decoupling between the self-diffusion coefficient and structural relaxation time, commonly described by a fractional SE relation. Whether and how the fractional SE exponents vary remains an ongoing debate, even for the simplest supercooled liquids. In this work, we numerically establish a universal relation between the self-diffusion coefficient and structural relaxation time by introducing characteristic scales that are revealed under the condition of constant dynamical heterogeneity. Moreover, this universal relation could also capture literature data for supercooled water and silica. Remarkably, we find that the fractional SE exponent is invariant across various supercooled liquids studied spanning a wide range of fragility, thereby challenging the prevailing view that the fractional SE exponent is correlated with fragility. Our study demonstrates that investigating dynamical heterogeneity yields more valuable insights into understanding glassy dynamics than expected.
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BibTeX
@misc{zhu2026universal,
title = {{Universal link between structural relaxation and self-diffusion in simple supercooled liquids}},
author = {Mingyu Zhu and Xinyu Chang and Licun Fu and Yiming Zheng and Lijin Wang},
howpublished = {arXiv},
year = {2026},
month = oct,
doi = {10.48550/arxiv.2610.22385},
eprint = {2610.22385},
archivePrefix = {arXiv},
url = {https://arxiv.org/abs/2610.22385},
note = {CC BY-NC-ND 4.0},
}
RIS
TY - UNPB
TI - Universal link between structural relaxation and self-diffusion in simple supercooled liquids
AU - Mingyu Zhu
AU - Xinyu Chang
AU - Licun Fu
AU - Yiming Zheng
AU - Lijin Wang
PY - 2026
DA - 2026/10/12
PB - arXiv
DO - 10.48550/arxiv.2610.22385
UR - https://arxiv.org/abs/2610.22385
AB - Despite a vigorous effort, a comprehensive and satisfactory understanding of the dynamics underlying the glass transition in finite-dimensional systems has not yet emerged. One key hallmark of supercooled liquids approaching the glass transition is the breakdown of the classical Stokes-Einstein (SE) relation, manifested as the decoupling between the self-diffusion coefficient and structural relaxation time, commonly described by a fractional SE relation. Whether and how the fractional SE exponents vary remains an ongoing debate, even for the simplest supercooled liquids. In this work, we numerically establish a universal relation between the self-diffusion coefficient and structural relaxation time by introducing characteristic scales that are revealed under the condition of constant dynamical heterogeneity. Moreover, this universal relation could also capture literature data for supercooled water and silica. Remarkably, we find that the fractional SE exponent is invariant across various supercooled liquids studied spanning a wide range of fragility, thereby challenging the prevailing view that the fractional SE exponent is correlated with fragility. Our study demonstrates that investigating dynamical heterogeneity yields more valuable insights into understanding glassy dynamics than expected.
ER -